Mass spectrometryMass spectrometry (MS) is an analytical technique that is used to measure the mass-to-charge ratio of ions. The results are presented as a mass spectrum, a plot of intensity as a function of the mass-to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as well as complex mixtures. A mass spectrum is a type of plot of the ion signal as a function of the mass-to-charge ratio.
Arctic sea ice declineSea ice in the Arctic has declined in recent decades in area and volume due to climate change. It has been melting more in summer than it refreezes in winter. Global warming, caused by greenhouse gas forcing is responsible for the decline in Arctic sea ice. The decline of sea ice in the Arctic has been accelerating during the early twenty‐first century, with a decline rate of 4.7% per decade (it has declined over 50% since the first satellite records). It is also thought that summertime sea ice will cease to exist sometime during the 21st century.
Resolution (mass spectrometry)In mass spectrometry, resolution is a measure of the ability to distinguish two peaks of slightly different mass-to-charge ratios ΔM, in a mass spectrum. There are two different definitions of resolution and resolving power in mass spectrometry. The IUPAC definition for resolution in mass spectrometry is Where a larger resolution indicates a better separation of peaks. This definition is used in a number of mass spectrometry texts. This use is also implied by the term "high-resolution mass spectrometry.
Liquid chromatography–mass spectrometryLiquid chromatography–mass spectrometry (LC–MS) is an analytical chemistry technique that combines the physical separation capabilities of liquid chromatography (or HPLC) with the mass analysis capabilities of mass spectrometry (MS). Coupled chromatography - MS systems are popular in chemical analysis because the individual capabilities of each technique are enhanced synergistically. While liquid chromatography separates mixtures with multiple components, mass spectrometry provides spectral information that may help to identify (or confirm the suspected identity of) each separated component.
Ion-mobility spectrometry–mass spectrometryIon mobility spectrometry–mass spectrometry (IMS-MS) is an analytical chemistry method that separates gas phase ions based on their interaction with a collision gas and their masses. In the first step, the ions are separated according to their mobility through a buffer gas on a millisecond timescale using an ion mobility spectrometer. The separated ions are then introduced into a mass analyzer in a second step where their mass-to-charge ratios can be determined on a microsecond timescale.
Greenland ice sheetThe Greenland ice sheet (Grønlands indlandsis, Sermersuaq) is a vast body of ice covering , roughly near 80% of the surface of Greenland. It is sometimes referred to as an ice cap, or under the term inland ice, or its Danish equivalent, indlandsis. The acronym GIS is frequently used in the scientific literature. It is the second largest ice body in the world, after the Antarctic ice sheet. The ice sheet is almost long in a north–south direction, and its greatest width is at a latitude of 77°N, near its northern margin.
Time-of-flight mass spectrometryTime-of-flight mass spectrometry (TOFMS) is a method of mass spectrometry in which an ion's mass-to-charge ratio is determined by a time of flight measurement. Ions are accelerated by an electric field of known strength. This acceleration results in an ion having the same kinetic energy as any other ion that has the same charge. The velocity of the ion depends on the mass-to-charge ratio (heavier ions of the same charge reach lower speeds, although ions with higher charge will also increase in velocity).
Tandem mass spectrometryTandem mass spectrometry, also known as MS/MS or MS2, is a technique in instrumental analysis where two or more mass analyzers are coupled together using an additional reaction step to increase their abilities to analyse chemical samples. A common use of tandem MS is the analysis of biomolecules, such as proteins and peptides. The molecules of a given sample are ionized and the first spectrometer (designated MS1) separates these ions by their mass-to-charge ratio (often given as m/z or m/Q).
Sea iceSea ice arises as seawater freezes. Because ice is less dense than water, it floats on the ocean's surface (as does fresh water ice, which has an even lower density). Sea ice covers about 7% of the Earth's surface and about 12% of the world's oceans. Much of the world's sea ice is enclosed within the polar ice packs in the Earth's polar regions: the Arctic ice pack of the Arctic Ocean and the Antarctic ice pack of the Southern Ocean.
Little Ice AgeThe Little Ice Age (LIA) was a period of regional cooling, particularly pronounced in the North Atlantic region. It was not a true ice age of global extent. The term was introduced into scientific literature by François E. Matthes in 1939. The period has been conventionally defined as extending from the 16th to the 19th centuries, but some experts prefer an alternative timespan from about 1300 to about 1850. The NASA Earth Observatory notes three particularly cold intervals.
