High-useful yield and new autoionizing state of resonantly ionized tungsten
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Uranium isotopic signatures can be harnessed to monitor the reductive remediation of subsurface contamination or to reconstruct paleo-redox environments. However, the mechanistic underpinnings of the isotope fractionation associated with U reduction remain ...
High-intensity extreme ultraviolet (XUV) pulses from a free-electron laser can be used to create a nanoplasma in clusters. In reference Michiels et al (2020 Phys. Chem. Chem. Phys. 22 7828-34) we investigated the formation of excited states in an XUV-induc ...
To date, the vast majority of studies seeking to link discharge to solute concentrations have been based on representations of fluid age distributions in watersheds that are time-invariant. As increasingly detailed spatial and temporal datasets become avai ...
New Haven2023
Stable mercury (Hg) isotope ratios are an emerging tracer for biogeochemical transformations in environmental systems, but their application requires knowledge of isotopic enrichment factors for individual processes. We investigated Hg isotope fractionatio ...
Washington2023
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Stable water isotopes are natural tracers allowing to reconstruct the history of a water parcel. They are used as climate proxies and to better understand the hydrological cycle. The snow isotopic composition is directly influenced by temperatures and atmo ...
2022
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The two-step electron transfer during bacterial reduction of UVI to UIV is typically accompanied by mass-independent fractionation of the 238U and 235U isotopes, whereby the heavy isotope accumulates in the reduced product. However, the role of the UV inte ...
2024
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Uranium (U) isotopes are suggested as a tool to trace U reduction. However, noncrystalline U(IV), formed predominantly in near-surface environments, may be complexed and remobilized using ligands under anoxic conditions. This may cause additional U isotope ...
The stable isotopes of hydrogen and oxygen in xylem water are often used to investigate tree water sources. But this traditional approach does not acknowledge the contribution of water stored in the phloem to transpiration and how this may affect xylem wat ...
Hexavalent uranium (U(VI)) is reduced to tetravalent uranium (U(IV)) by microorganisms (e.g., Geobacter or Shewanella spp.) as well as by abiotic reductants such as sulfide or Fe(II) species. During reduction, the heavy isotope (238U) is typically enriched ...
The stable isotopes of hydrogen and oxygen (delta H-2 and delta O-18, respectively) have been widely used to investigate tree water source partitioning. These tracers have shed new light on patterns of tree water use in time and space. However, there are s ...