Benefits and Scepticism of Ecolabels as Accountability Mechanism

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Development of remote C-H bond functionalization of redox-active alcohol derivatives and oxidative transformations under photoredox catalysis

The development of radical-based remote C(sp3)-H functionalizations of redox-active alcohol derivatives, oxidative cycloaddition and rearrangement transformations under visible light photocatalysis constitute the basis of this thesis. The first chapter des ...

EPFL2021

Ordinary varieties with trivial canonical bundle are not uniruled

Zsolt Patakfalvi, Maciej Emilian Zdanowicz

We prove that smooth, projective, K-trivial, weakly ordinary varieties over a perfect field of characteristic p>0 are not geometrically uniruled. We also show a singular version of our theorem, which is sharp in multiple aspects. Our work, together with La ...

2021

Seeking methods for improving sustainability in the extractive sector

Farnaz Eslamishoar

Extractive resources are indisputably a necessary component of international sustainable development. Despite current advancements in the circular economy, world production needs for raw materials are ever increasing, and still a long way remains for it to ...

EPFL2021

Global Frobenius liftability I

Maciej Emilian Zdanowicz

We formulate a conjecture characterizing smooth projective varieties in positive characteristic whose Frobenius morphism can be lifted modulo p(2)-we expect that such varieties, after a finite stale cover, admit a toric fibration over an ordinary abelian v ...

2021

Colloidal Synthesis of Cu-M-S (M = V, Cr, Mn) Nanocrystals by Tuning the Copper Precursor Reactivity

Raffaella Buonsanti, Seyedehbehnaz Varandili, Valeria Mantella, James Richard Pankhurst

New ternary and higher order inorganic materials are needed for a large variety of applications, yet their synthesis still represents a chemistry challenge. Herein, we focus on the synthesis of Cu-M-S nanocrystals (where M = V, Cr, Mn) via a wet-chemistry ...

2020

Unsupervised Representation Learning for Gaze Estimation

Jean-Marc Odobez, Yu Yu

Although automatic gaze estimation is very important to a large variety of application areas, it is difficult to train accurate and robust gaze models, in great part due to the difficulty in collecting large and diverse data (annotating 3D gaze is expensiv ...

IEEE2020

A comprehensive error rate for multiple testing

Jean-Philippe Thiran, Dimitri Nestor Alice Van De Ville, Stephan Morgenthaler, Djalel Eddine Meskaldji

Over the last two decades, a large variety of type I error rates and control procedures have been proposed in the field of multiple hypotheses testing. This paper proposes a framework that includes many existing proposals by investigating procedures in whi ...

SPRINGER2020

A semantic-driven approach toward Industry 4.0

Sangje Cho

The current manufacturing trend is towards sustainability. Due to the degradation of natural resources and the accumulation of waste with an increase in the world population and in the consumption of goods, many countries attempt to switch from a linear to ...

EPFL2020

Modular Chiral N-Heterocyclic Carbene Ligands for the Nickel-Catalyzed Enantioselective C-H Functionalization of Heterocycles

Nicolai Cramer, Johannes Diesel

N-Heterocyclic carbenes (NHCs) are the ligands of choice in a large variety of transformations entailing different transition metals. However, the number and variety of chiral NHCs suitable as stereo-controlling ligands in asymmetric catalysis remains limi ...

2020

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Global Frobenius liftability I

Maciej Emilian Zdanowicz

2021

Development of remote C-H bond functionalization of redox-active alcohol derivatives and oxidative transformations under photoredox catalysis

Alexandre Julien Florent Leclair

EPFL2021

Modular Chiral N-Heterocyclic Carbene Ligands for the Nickel-Catalyzed Enantioselective C-H Functionalization of Heterocycles

Nicolai Cramer, Johannes Diesel

2020