A Kinetic Model for Adosorption and Transfer of Ionic Species at Polarized Liquid|Liquid Interfaces as Studied by Potential Modulated Fluorescence Spectroscopy
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The adsorption of ions at the interface between two immiscible electrolyte solutions (ITIES) is primarily controlled by the potential distribution across the interface, which in turn is influenced by the adsorption process. In the present paper, we simulat ...
Hexanethiolate monolayer-protected gold nanoclusters (MPCs) were used as redox quenchers at the polarizable water/1,2-dichloroethane (DCE) interface. Photocurrent responses originating from the heterogeneous quenching of photoexcited water soluble porphyri ...
One possibility for the removal of volatile organic compounds (VOCs) is catalytic oxidation. For the removal of VOCs in low concentration (≲ 3000 ppmv for propane) it is not possible to sustain the required oxidation temperature over the catalyst wit ...
The interface between two immiscible electrolyte solutions provides a well-defined framework for fundamental studies of heterogeneous charge transfer processes. Recent developments in experimental methodology have allowed addressing the kinetics of electro ...
A new technique has been developed that combines evanescent-field optical sensing with electrochem. control of surface adsorption processes. This new technique, termed "electrochem. optical wave-guide lightmode spectroscopy" (EC-OWLS), proved efficient i ...
We present an experimental and theoretical investigation into time- vs. frequency-domain femtosecond sum frequency spectroscopy at the metal-liquid interface. Although frequency and time-domain measurements are theoretically equivalent it is demonstrated h ...
The heterodimer formed by electrostatic association of zinc(II) meso-tetrakis(N-methylpyridyl)porphyrin (ZnTMPyP) and zinc(II) meso-tetrakis(p-sulfonatophenyl)porphyrin (ZnTPPS) exhibits a strong affinity for the interface between water and 1,2-dichloroeth ...
The interface between two immiscible electrolyte solutions (ITIES), or liquid|liquid interface, provides a defect-free junction for fundamental studies of adsorption phenomena, heterogeneous charge transfer reactions, and phase-formation processes. Recent ...
The voltage induced assembly and photoreactivity of cadmium selenide (CdSe) nanoparticles protected by mercaptosuccinic acid are studied at the polarisable interface between water and 1,2-dichloroethane electrolyte solutions. Cyclic voltammograms and admit ...
Two-phase liquid system IA(w)jIX(o) comprising the interface between the aqueous solution (w) of uni-univalent electrolyte IA and an organic solvent solution (o) of a uni-univalent electrolyte IX with the common cation I+ is considered as a simple model of ...