Biomimetic Catalysis with Immobilised Organometallic Ruthenium(II) Complexes: Substrate and Regioselective Transfer Hydrogenation of Ketones
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In this thesis, new aspects of the chemistry of Cp^Ru complexes are described (Cp^=η5-1-methoxy-2,4-tert-butyl-3-neopentylcyclopentadienyl).Despite many similarities with CpRu and Cp*Ru compounds, Cp^Ru complexes display a unique reactivity because of the ...
Investigations of ruthenium halfsandwich complexes have mostly focused on Cp and Cp* based derivatives due to the availability of easily accessible starting materials. However, it is interesting to have complexes with substituted cyclopentadienyl ligands i ...
Water-dispersible, polymer-wrapped nanocrystals are highly sought after for use in biol. and chem., from nanomedicine to catalysis. The hydrophobicity of their native ligand shell, however, is a significant barrier to their aq. transfer as single particles ...
This thesis encompasses work on the coordination chemistry and catalytic activity of half sandwich ruthenium(II)-arene phosphine complexes. The investigation of phosphine dissociation and association reactions of these complexes represents the unifying the ...
Multicomponent reactions between 1,4-benzenediboronic acid, catechol, and different pyridyl ligands are reported. The condensation of 1,4-benzenediboronic acid with catechol gives 1,4-bis(benzodioxaborole)benzene. Upon crystallization, the ester aggregates ...
Pyridylferrocene and imidazolylferrocene arene-Ru complexes [Ru(η6-arene)(L)Cl2] where L = NC5H4CH2NHOCC5H4FeC5H5, arene = p-iPrC6H4Me (1) or C6Me6 (2); L = NC3H3N(CH2)2O2CC5H4FeC5H5, arene = p-iPrC6H4Me (3) or C6Me6 (4), and diruthenium-arene complexes [R ...
While the bulk structure of a material determines its mechanical properties, its surface plays a key role when interactions with the environment are important. Nowadays materials in bio- and nanotechnology are required to possess very complex functionaliti ...
Virus filtration by size exclusion is a robust means of eliminating viruses in blood or pharma products. Porous polymer membranes with a narrow size distribution are used to allow passage of the protein product but retain viruses. The chosen polymer must r ...
Hydrolytically degradable polymer brushes would represent an interesting platform for the development of functional coatings for various biomaterials applications In this manuscript, the surface- initiated atom transfer radical copolymerization of 5.6-benz ...
This manuscript reports on the post-polymerization modification of poly(glycidyl methacrylate) (PGMA) and PGMA-co-poly(2-(diethylamino)ethyl methacrylate) (PGMA(x)-co-PDEAEMA(y)) (co)polymer brushes prepared via surface-initiated atom transfer radical poly ...