Publication
ZSM-5 coatings on stainless steel grids in one-step benzene hydroxylation to phenol by N2O: Reaction kinetics study
Related publications (37)
Kinetic Network Modeling of the Catalytic Upgrading of Biomass's Acetate Fraction to Aromatics
Jeremy Luterbacher, Jher Hau Yeap, Bartosz Rozmyslowicz, Ahmed Mohamed Ibrahim Elkhaiary
The acetate fraction is the fourth most abundant fraction by weight in many plant species and can be easily extracted as acetic acid in high yields. We have previously shown that acetic acid obtained from steam pretreated beech wood could be upgraded in a ...
Washington2023Imaging of Chemical Kinetics at the Water–Water Interface in a Free-Flowing Liquid Flat-Jet
Andreas Osterwalder, Bruno Credidio
We present chemical kinetics measurements of the luminol oxidation chemiluminescence (CL) reaction at the interface between two aqueous solutions, using liquid jet technology. Free-flowing liquid microjets are a relatively recent development that have foun ...
2022A method for the reliable and reproducible precipitation of phase pure high Ca/Si ratio (>1.5) synthetic calcium silicate hydrates (C-S-H)
Karen Scrivener, Paul Bowen, Maya Nicole Harris, Grace Simpson
Various methods have been developed to synthesize C-S-H; however, these methods have only allowed for the successful production of pure-phase C-S-H with Ca:Si of 1.5 or less. Attempts to form higher Ca:Si ratios by these methods gives C-S-H (Ca:Si 1.5 or l ...
PERGAMON-ELSEVIER SCIENCE LTD2022Improved Modeling of Sediment Oxygen Kinetics and Fluxes in Lakes and Reservoirs
To understand water quality degradation during hypoxia, we need to understand sediment oxygen fluxes, the main oxygen sink in shallow hypolimnia. Kinetic models, which integrate diffusion and consumption of dissolved oxygen (DO) in sediments, usually assume ...
2020Micropollutant Oxidation Studied by Quantum Chemical Computations: Methodology and Applications to Thermodynamics, Kinetics, and Reaction Mechanisms
Urs von Gunten, Minju Lee, Peter Rudolf Tentscher
The abatement of organic micropollutants during oxidation processes has become an emerging issue for various urban water systems such as drinking water, wastewater, and water reuse. Reaction kinetics and mechanisms play an important role in terms of effici ...
AMER CHEMICAL SOC2019Investigation of the heterogeneously catalysed gas phase CO2 hydrogenation reaction: Development of analysis methods and reaction analysis on pristine metal catalysts
Robin Tobias Andreas Mutschler
The aim of this thesis is to contribute to the development of analysis methods that enable an improved investigation of the CO2 hydrogenation reaction such as quantitative mass spectrometry and infrared thermography. Furthermore, the contribution is in the ...
EPFL2019Control Theory Concepts for Modeling Uncertainty in Enzyme Kinetics of Biochemical Networks
Vassily Hatzimanikatis, Ljubisa Miskovic, Georgios Savoglidis, Milenko Tokic
Analysis of the dynamic and steady-state properties of biochemical networks hinges on information about the parameters of enzyme kinetics. The lack of experimental data characterizing enzyme activities and kinetics along with the associated uncertainties i ...
2019Mechanism and Kinetics of Propane Dehydrogenation and Cracking over Ga/H-MFI Prepared via Vapor-Phase Exchange of H-MFI with GaCI3
In this study, the mechanism and kinetics of C3H8 dehydrogenation and cracking are examined over Ga/H-MFI catalysts prepared via vapor-phase exchange of H-MFI with GaCl3. The present study demonstrates that GaH cations are the active centers for C3H8 ...
2019Quantum-state-controlled channel branching in cold Ne(3P2)+Ar chemi-ionization
Andreas Osterwalder, Sean Dennis Steven Gordon, Junwen Zou, Silvia Tanteri
A prerequisite to gain a complete understanding of the most basic aspects of chemical reactions is the ability to perform experiments with complete control over the reactant degrees of freedom. By controlling these, details of a reaction mechanism can be i ...
2018Fast real time and quantitative gas analysis method for the investigation of the CO2 reduction reaction mechanism
Andreas Züttel, Emanuele Moioli, Wen Luo, Robin Tobias Andreas Mutschler
We present a new fast real time and quantitative gas analysis method by means of mass spectrometry (MS), which has approximately an order of magnitude faster sampling rate in comparison with a traditional gas chromatography. The method is presented and dis ...
AMER INST PHYSICS2018