Concept
Réarrangement de Hofmann
Publications associées (26)
Sustainable, recyclable and biodegradable castor oil-derived elastomers enabled by dynamic acetoacetyl formed amides
Developing sustainable, recyclable, and biodegradable elastomers with the mechanical properties comparable to commercial polymers presents a formidable challenge. To this end, we synthesize a kind of mechanically robust elastomers cross -linked by acetoace ...
Elsevier Science Sa2024Enantioselective Total Synthesis of (+)-Stephadiamine
Qian Wang, Jieping Zhu, Baochao Yang, Guang Li
An asymmetric synthesis of (+)-stephadiamine has been accomplished featuring (a) an enantioselective dearomatizative Michael addition to generate a quaternary stereocenter; (b) a domino sequence involving reductive generation of nitrone from γ-nitro ketone ...
2023Degradation study of a reversible solid oxide cell (rSOC) short stack using distribution of relaxation times (DRT) analysis
Jan Van Herle, Stefan Diethelm, Philippe Aubin, Suhas Nuggehalli Sampathkumar, Maria del Mar Perez Fortes
Reversible solid oxide cells (rSOC) can convert excess electricity to valuable fuels in electrolysis cell mode (SOEC) and reverse the reaction in fuel cell mode (SOFC). In this work, a five - cell rSOC short stack, integrating fuel electrode (Ni-YSZ) suppo ...
PERGAMON-ELSEVIER SCIENCE LTD2022Diamine Synthesis via the Nitrogen-Directed Azidation of sigma- and pi-C-C Bonds
Diamines are essential building blocks for the synthesis of agrochemicals, drugs, and organic materials, yet their synthesis remains challenging, as both nitrogens need to be differentiated and diverse substitution patterns (1,2, 1,3, or 1,4) are required. ...
AMER CHEMICAL SOC2021Potential Induced Degradation Mechanism in Rear-Emitter Bifacial Silicon Heterojunction Solar Cells Encapsulated in Different Module Structures
Christophe Ballif, Quentin Thomas Jeangros, Alessandro Francesco Aldo Virtuani, Olatz Arriaga Arruti, Luca Gnocchi
Recent studies showed that silicon heterojunction (SHJ) solar cells can be prone to potential induced degradation (PID) when encapsulated with ethylene vinyl acetate (EVA). Here, to gain understanding in the role of EVA, we perform PID test in humid condit ...
IEEE2021Insertion of germanium atoms in high- nuclearity rhodium carbonyl compounds: synthesis, characterization and preliminary biological activity of the heterometallic [ Rh13Ge( CO) 25] 3-, [ Rh14Ge2( CO) 30] 2-and [ Rh12Ge( CO) 27] 4-clusters+
Paul Joseph Dyson, Silvia Ruggieri
The reaction of the Rh-7(CO)(16) cluster anion with Ge2+ salts, in different stoichiometric ratios and under different atmospheres, leads to the formation of new heterometallic Rh-Ge clusters, representing the first known examples of Rh carbonyl comp ...
ROYAL SOC CHEMISTRY2018Organocatalytic Enantioselective Acyloin Rearrangement of α-Hydroxy Acetals to α-Alkoxy Ketones
Qian Wang, Jieping Zhu, Hua Wu
We report an unprecedented organocatalytic enantioselective acyloin rearrangement of alpha,alpha-disubstituted alpha-hydroxy acetals. In the presence of a catalytic amount of chiral binol-derived N-triflyl phosphoramide, alpha-hydroxy acetals rearranged to ...
Wiley-Blackwell2017Palladium-Catalyzed Three-Component Reaction of Propargyl Carbonates, Isocyanides, and Alcohols or Water: Switchable Synthesis of Pyrroles and Its Bicyclic Analogues
Qian Wang, Jieping Zhu, Guanyinsheng Qiu
In the presence of a catalytic amount of Pd(OAc)2 and a stoichiometric amount of tert-butylamine, the reaction of propargyl carbonates, isocyanides, and alcohols afforded polysubstituted aminopyrroles in good yields. Using water as a nucleophile instead of ...
American Chemical Society2017Uranium(IV) Terminal Hydrosulfido and Sulfido Complexes: The Nature of the Uranium–Sulfur Bond
Marinella Mazzanti, Julie Renée Michelle Andrez
Herein, we report the synthesis and characterization of a series of terminal uranium(IV) hydrosulfido and sulfido complexes, supported by the hexadentate, tacn-based ligand framework (Ad,MeArO)3tacn3– (= trianion of 1,4,7-tris(3-adamantyl-5-methyl-2-hydrox ...
Royal Soc Chemistry2016