Electron-beam processing

Résumé

Electron-beam processing or electron irradiation (EBI) is a process that involves using electrons, usually of high energy, to treat an object for a variety of purposes. This may take place under elevated temperatures and nitrogen atmosphere. Possible uses for electron irradiation include sterilization, alteration of gemstone colors, and cross-linking of polymers. Electron energies typically vary from the keV to MeV range, depending on the depth of penetration required. The irradiation dose is usually measured in grays but also in Mrads (1 Gy is equivalent to 100 rad). The basic components of a typical electron-beam processing device include: an electron gun (consisting of a cathode, grid, and anode), used to generate and accelerate the primary beam; and, a magnetic optical (focusing and deflection) system, used for controlling the way in which the electron beam impinges on the material being processed (the "workpiece"). In opera

Source officielle

https://en.wikipedia.org/wiki/Electron-beam_processing

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Virus filtration by size exclusion is a robust means of eliminating viruses in blood or pharma products. Porous polymer membranes with a narrow size distribution are used to allow passage of the protein product but retain viruses. The chosen polymer must resist process-induced physical and chemical wear and is therefore generally inert and hydrophobic material. When filtrating potentially heterogeneous products such as IgG from pooled blood samples, protein adsorption on the polymer surface causes high fouling. This eventually blocks the filter and reduces total filtration volume. A solution to this adsorption problem is to graft a hydrophilic gel-like polymer layer on the membrane inner surface to reduce protein adsorption. The surface properties are thus changed while retaining the stability of the bulk polymer. The grafting was initiated with an electron beam, which creates free radicals by unspecific scission of the polymer backbone through electron irradiation. Two acrylate monomers were used for polymerization, a monofunctional monomer and a bifunctional one, used as a crosslinker to form the gel structure. Two different grafting method were tested. The first grafting method is simultaneous grafting, where the membrane is impregnated with the monomer solution then irradiated. Initiation and polymerization thus occur almost simultaneously. The grafted membrane properties were assessed using flow measurements, protein adsorption tests, FTIR absorbance measurements, virus retention tests and filter integrity tests. Comparing the various grafting approaches, it can be seen that simultaneous grafting lowers considerably protein adsorption, to the price of a highly reduced buffer flow. These filters therefore run slowly but can process more volume before fouling. The sequential grafting method using peroxides as initiators did not show significant filtration improvements compared to the reference membrane when the solution with monomer and crosslinker was used. However, when only monofunctional monomer was used for peroxidation grafting, the protein filtration capacity was increased with limited buffer flow loss. Generally, the sequential method is interesting for graft polymerization of porous membranes because it allows higher degree of grafting and the versatile grafting parameters involved give many development options depending on the application

2010

Chargement

Here, we report a facile irradiation-assisted route to fabricate sub-10 nm Ag nanowires fromoxide supports using a TEM. The obtained Ag nanowires show a tunable length/diameter aspect ratio with a minimum diameter of about 9.5 nm. Moreover, the nucleation and growth dynamics of Ag nanowires were uncovered from TEM observations.

ROYAL SOC CHEMISTRY2020

Chargement

Defect chemistry of methylammonium lead iodide

Alessandro Senocrate

The present work deals with the defect chemistry and charge transport properties in halide perovskites, and in particular in the archetypal methylammonium lead iodide. These materials are extensively researched due to their very promising application as light-harvesters in solar cells and in other optoelectronic devices. Notwithstanding the numerous studies dealing with these materials (especially with their optical and electronic properties, and with device application), a significant portion of the underlying physics and chemistry is still poorly understood. Indeed, the physico-chemical features behind their exceptional photo-electrochemical properties are still largely unknown. Moreover, these materials suffer from severe degradation processes presently impeding their practical application. In addition, the charge transport in these materials is not purely electronic, but rather shows a significant ionic portion due to mobile ionic defects. The nature of such ion conduction, alongside its effect on the photo-electrochemical properties and on the materials stability, has never been systematically investigated. The study of these aspects is the aim of this thesis, where: At first, we study the charge transport properties of methylammonium lead iodide, with particular attention to the ionic contribution, and we perform a defect chemical study of the compound. We show how the ionic conductivity, in equilibrium conditions, can be unambiguously assigned to mobile iodine vacancies, with an electronic contribution due to electron holes or conduction electron depending on the iodine activity. Secondly, we investigate the light effect on the charge transport previously characterized. Alongside an expected increase of the electronic contribution, we observe a striking enhancement of ionic conductivity in methylammonium lead iodide upon illumination. This remarkable observation is of fundamental relevance for both photovoltaics and solid state ionics fields. Here we also discuss a mechanism for such photo-enhanced ion conduction that relies on electron-ion interaction. Subsequently, we analyze methylammonium lead iodide and other hybrid halide perovskites under oxygen exposure, both in the dark and under illumination. We show that light strongly affects the kinetics of oxygen interaction, so much so that under illumination methylammonium lead iodide completely degrades, while it is metastable in the dark. The oxygen, when incorporated in a sufficient amount in the lattice, also acts as acceptor dopant, greatly varying the ionic and electronic conductivities. We then investigate stability of several halide perovskites with respect to temperature, oxygen, and illumination through thermodynamic considerations. Here we show how many of these processes are expected to be extremely severe for some of the compounds, underlining an important -and intrinsic- bottleneck for the application of these materials. At last, we investigate the short-range ion dynamics in methylammonium lead iodide, since these are linked to stability and electronic transport properties. Here, we show that methylammonium dynamics conforms well to a fast bi-axial rotation becoming isotropic in the cubic phase. In the inorganic lattice, a strong nuclear coupling between Pb and I is present, alongside highly active iodine dynamics.

EPFL2018

Chargement

Defect chemistry of methylammonium lead iodide

Alessandro Senocrate

EPFL2018

2010