Concept

X-ray Raman scattering

Résumé
X-ray Raman scattering (XRS) is non-resonant inelastic scattering of X-rays from core electrons. It is analogous to vibrational Raman scattering, which is a widely used tool in optical spectroscopy, with the difference being that the wavelengths of the exciting photons fall in the X-ray regime and the corresponding excitations are from deep core electrons. XRS is an element-specific spectroscopic tool for studying the electronic structure of matter. In particular, it probes the excited-state density of states (DOS) of an atomic species in a sample. Description XRS is an inelastic X-ray scattering process, in which a high-energy X-ray photon gives energy to a core electron, exciting it to an unoccupied state. The process is in principle analogous to X-ray absorption (XAS), but the energy transfer plays the role of the X-ray photon energy absorbed in X-ray absorption, exactly as in Raman scattering in optics vibrational low-energy excitations can be observed by studying th
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