Effet Jahn-Teller

Résumé

vignette|L’effet Jahn-Teller est responsable de la distorsion du complexe hexaaquacuivre(II), , qui devrait posséder une géométrie octaédrique. Les deux liaisons Cu-O axiales mesurent environ , alors que les quatre liaisons Cu-O équatoriales mesurent environ . L’effet Jahn-Teller, connu aussi en tant que « Distorsion Jahn-Teller », décrit la distorsion de la géométrie des molécules non linéaires dans certaines situations. Historiquement, cet effet a été proposé dans un théorème publié en 1937 par Hermann Arthur Jahn et Edward Teller, dans lequel ils démontrent que toute molécule non linéaire possédant un niveau électronique fondamental dégénéré subira une distorsion géométrique qui lèvera cette dégénérescence, ce qui aura pour effet de diminuer l’énergie totale de la molécule. Cet effet est observé dans les complexes octaédriques de certains métaux de transition hexacoordonnés, en particulier, le cuivre(), le chrome() et le manganèse(). Placées dans un champ de ligands octaédrique, l

Source officielle

https://fr.wikipedia.org/wiki/Effet_Jahn-Teller

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Publications associées (32)

Electronic structural details of donor-vacancy complexes in Si-doped Ge and Ge-doped Si

Alexandra Sarabando de Carvalho

We present a detailed picture of the electronic structure of donor-vacancy complexes in Ge-doped silicon and Si-doped germanium Clusters to mimic Si-rich and Ge-rich SiGe alloys, respectively Jahn-Teller effects and electrical levels were investigated in both Si-rich and Ge-rich end compositions It is shown that while Ge atoms act as efficient traps for mobile E-centers in Si-rich alloys, Si atoms in Ge-rich material do not have this ability A detailed linear combination of atomic orbitals model is proposed for VP-Ge and VP-Si complexes in Si1-xGex and Ge1-xSix, where the orbital filling order is driven by the larger electron affinity of Si atoms when compared to Ge. (C) 2009 Elsevier B.V. All rights reserved

2010

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Understanding the elementary steps involved in a chemical reaction forms the cornerstone of physical chemistry research. One way to deepen this understanding is by studying chemical and physical processes using linear and nonlinear spectroscopic techniques. However, the outcomes of such experiments can be difficult to decipher due to the interweaving of several effects. Therefore, in order to help experimentalists to disentangle such spectra, the role of theorists is to develop efficient tools that are able to accurately describe molecular systems. The starting point of such tools is solving the time-dependent Schrödinger equation. In this thesis, after implementing geometric integrators, which are based on a combination of the split-operator algorithm and Magnus expansion, for the exact nonadiabatic quantum dynamics of a molecule interacting with a time-dependent electromagnetic field, we derive and implement these geometric integrators for the time-dependent perturbation theory, the Condon, rotating-wave, and ultrashort-pulse approximations, as well as every possible combination thereof. As verified in several model systems, these integrators exactly preserve the geometric invariants, and achieve an arbitrary prescribed order of accuracy in the time step and an exponential convergence in the grid spacing. We also explore in more detail the ultrashort-pulse approximation and derive an analytical expression for the combination with the time-dependent perturbation theory; this expression significantly accelerates numerical calculations. We show that in the limit of the zero pulse width, the d-pulse approximation is recovered. We illustrate the performance of the introduced approximations, using a three-dimensional model of pyrazine, in which it is essential to go beyond the d-pulse limit in order to describe the dynamics correctly. The high-order algorithms are also applied to the photodissociation dynamics of iodomethane (CH3I), following its excitation to the A band. We implement a general split-operator with both discrete-variable and finite-basis representations that can treat one non-Cartesian, such as angular coordinate. To test the effect of various degrees of freedom and of the nonadiabatic dynamics, we apply these algorithms to one-, two-, and three-dimensional models of iodomethane, both in the presence and in the absence of nonadiabatic couplings. A full quantum calculation is, however, limited to problems with low dimensionality (approximately ten degrees of freedom). Beyond this, one must seek an affordable balance between computational efficiency and physical accuracy and can employ, for example, semiclassical methods that are based on classical trajectories. A simple semiclassical approximation that can treat larger systems and requires only local knowledge of the potential is the on-the-fly ab initio thawed Gaussian approximation. We implement a generalization of the method that goes beyond the Franck-Condon approximation and treats Herzberg-Teller active molecules. Our method is used to compute absorption spectra of phenyl radical and of benzene, for which the Herzberg-Teller contribution is essential.

EPFL2017

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We present an electro-optical model of a three-layer phosphorescent OLED which accurately describes the measured current efficiency and transient electroluminescence decay for different biases. Central findings are a bias-dependent emission zone, which influences light outcoupling as well as exciton quenching, and the presence of strong triplet-polaron quenching even at low bias. The measured current efficiency initially increases up to 9 V before it decreases, where the increase is found to be caused by reduced triplet-polaron quenching with holes, while the decrease is caused by a reduced light outcoupling and increased triplet-triplet annihilation. The numerical model allows identifying the individual contributions of the exciton continuity equation and explains the electroluminescence decay, which deviates significantly from a mono-exponential decay due to the dominating influence of exciton generation and quenching after the external bias is removed.

2019

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EPFL2017