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Hot alkyne! The in situ generation of Ethynyl-1,2-BenziodoXol-3(1H)-one (EBX) from the corresponding silyl protected reagent using TBAF is reported. EBX displayed exceptional acetylene transfer ability to stabilized enolates, even at –78 °C. The mild react ...
The use of zeolites for catalytic reactions is a field in continuous development. Since it was demonstrated that metal-zeolites are efficient catalysts for NOx abatement, decomposition of nitrous oxide (N2O) over Fe-containing zeolites has attracted great ...
Using sun as the energy source, natural photosynthesis carries out a number of useful reactions such as oxidation of water to molecular oxygen and fixation of CO2 in the form of sugars. These are achieved through a series of light-induced multielectron-tra ...
Carbon dioxide methanation was carried out over a series of Ni-CexZr1-xO2 catalysts prepared by a pseudo sol-gel method. The influence of CeO2/ZrO2 mass ratio and noble metal addition was investigated. The catalysts were subsequently characterized by means ...
A review of the state of the art gas turbine power plants designs with CO2 capture was performed to set up a list of technologies to be considered in a conceptual process superstructure. It has been found that the efficiency and economics of carbon dioxide ...
A highly efficient iron-catalyzed production of 5-hydroxymethylfurfural (HMF) from sugar is reported. The dehydration of fructose and sucrose has been studied in the presence of different iron salts and co-catalysts. As a result, it was found that fructose ...
The catalytic activity of [Cp*OsBr2(PPh3)] in conjunction with Mg has been evaluated for atom transfer radical addition (ATRA) and cyclization (ATRC) reactions. The Os complex enabled these reactions to be performed with similar efficiency as that of the a ...
Hydrogenation of bicarbonates in water: By using a ruthenium-based catalytic system hydrogenation of sodium bicarbonate was achieved in water in comparable high TONs and yields. The hydrogenation of sodium bicarbonate takes place with the catalytic system ...
Palladium nanohexagons were prepared using a seed-mediated method. Their catalytic performance in 2-methyl-3-butyn-2-ol hydrogenation was compared to the one of monodispersed Pd nanospheres. Quantitative correlations between initial turnover frequencies (T ...
New EU and US emissions regulations require the development of advanced after- treatment systems for non-road diesel engine exhausts. To help develop these at Liebherr Machines Bulle, the use of CFD has been adopted. The pro ject used two main models: one ...