Publications associées à Stœchiométrie

Yield prediction in parallel homogeneous assembly

We investigate the parallel assembly of two-dimensional, geometrically-closed modular target structures out of homogeneous sets of macroscopic components of varying anisotropy. The yield predicted by a chemical reaction network (CRN)-based model is quantit ...

Royal Society of Chemistry2017

On Decoupling Rate Processes in Chemical Reaction Systems - Methods and Applications

Dominique Bonvin, Julien Léo Billeter, Michael Amrhein, Sriniketh Srinivasan, Diogo Filipe Mateus Rodrigues

Models of chemical reaction systems can be complex as they need to include information regarding the reactions and the mass and heat transfers. The commonly used state variables, namely, concentrations and temperatures, express the interplay between many p ...

Elsevier2017

Palladium-Catalyzed Three-Component Reaction of Propargyl Carbonates, Isocyanides, and Alcohols or Water: Switchable Synthesis of Pyrroles and Its Bicyclic Analogues

Qian Wang, Jieping Zhu, Guanyinsheng Qiu

In the presence of a catalytic amount of Pd(OAc)2 and a stoichiometric amount of tert-butylamine, the reaction of propargyl carbonates, isocyanides, and alcohols afforded polysubstituted aminopyrroles in good yields. Using water as a nucleophile instead of ...

American Chemical Society2017

Nucleophilic Reactivity of a Nitride-Bridged Diuranium(IV) Complex: CO2 and CS2 Functionalization

Marinella Mazzanti, Lucile Sylvie Danielle Chatelain, Marta Falcone

Thermolysis of the nitride-bridged diuranium(IV) complex Cs{(-N)U(OSi((OBu)-Bu-t)(3))(3)} (1) showed that the bridging nitride behaves as a strong nucleophile, promoting N-C bond formation by siloxide ligand fragmentation to yield an imido-bridged sil ...

2016

Rates of microbial hydrogen oxidation and sulfate reduction in Opalinus Clay rock

Rizlan Bernier-Latmani, Alexandre Bagnoud

Hydrogen gas (H2) may be produced by the anoxic corrosion of steel components in underground structures, such as geological repositories for radioactive waste. In such environments, hydrogen was shown to serve as an electron donor for autotrophic bacteria. ...

Elsevier2016

Atomic Scale Microstructure and Properties of Se-Deficient Two-Dimensional MoSe2

Andras Kis, Oleg Yazyev, Hannu-Pekka Komsa, Ming-Wei Chen, Artem Pulkin

We study the atomic scale microstructure of non-stoichiometric two-dimensional(2D) transition metal dichalcogenide MoSe2-x, by employing aberration-corrected high-resolution transmission electron microscopy. We show that a Se-deficit in single layers of Mo ...

Amer Chemical Soc2015

A Study of Dynamic Responses of E. coli Metabolism Upon Large Perturbations Using Large-Scale Kinetic Models

Vassily Hatzimanikatis, Ljubisa Miskovic, Georgios Fengos, Milenko Tokic

In recent years, constraint-based approaches have been widely used for analyzing cellular metabolism. These approaches use stoichiometric models for the characterization of the intracellular fluxes at steady state. Nonetheless, the stoichiometric models la ...

2015

Compound-specific carbon, nitrogen, and hydrogen isotope analysis of N-nitrosodimethylamine in aqueous solutions

Urs von Gunten, Stephanie Spahr

Mitigation of N-nitrosodimethylamine (NDMA) and other hazardous water disinfection byproducts (DBP) is currently hampered by a limited understanding of DBP formation mechanisms. Because variations of the stable isotope composition of NDMA can potentially r ...

Amer Chemical Soc2015

Manipulating the reaction path of the CO2 hydrogenation reaction in molecular sieves

Davide Ferri, Elsa Callini, Rolf Erni

We demonstrate that the kinetics of the Sabatier reaction catalysed by sorption catalysts depends on the nanostructure of the catalyst-sorbent system. The catalysts are prepared by ion exchange of a nickel nitrate solution in two zeolites with different po ...

Royal Society of Chemistry2015

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Stœchiométrie

Yield prediction in parallel homogeneous assembly

On Decoupling Rate Processes in Chemical Reaction Systems - Methods and Applications

Palladium-Catalyzed Three-Component Reaction of Propargyl Carbonates, Isocyanides, and Alcohols or Water: Switchable Synthesis of Pyrroles and Its Bicyclic Analogues

Nucleophilic Reactivity of a Nitride-Bridged Diuranium(IV) Complex: CO2 and CS2 Functionalization

Rates of microbial hydrogen oxidation and sulfate reduction in Opalinus Clay rock

Atomic Scale Microstructure and Properties of Se-Deficient Two-Dimensional MoSe2

A critical evaluation of proxy methods used to estimate the acidity of atmospheric particles

A Study of Dynamic Responses of E. coli Metabolism Upon Large Perturbations Using Large-Scale Kinetic Models

Compound-specific carbon, nitrogen, and hydrogen isotope analysis of N-nitrosodimethylamine in aqueous solutions

Manipulating the reaction path of the CO2 hydrogenation reaction in molecular sieves

Graph Chatbot

Chattez avec Graph Search

Rates of microbial hydrogen oxidation and sulfate reduction in Opalinus Clay rock

Manipulating the reaction path of the CO2 hydrogenation reaction in molecular sieves

Yield prediction in parallel homogeneous assembly

A critical evaluation of proxy methods used to estimate the acidity of atmospheric particles

A Study of Dynamic Responses of E. coli Metabolism Upon Large Perturbations Using Large-Scale Kinetic Models

Compound-specific carbon, nitrogen, and hydrogen isotope analysis of N-nitrosodimethylamine in aqueous solutions

Palladium-Catalyzed Three-Component Reaction of Propargyl Carbonates, Isocyanides, and Alcohols or Water: Switchable Synthesis of Pyrroles and Its Bicyclic Analogues

On Decoupling Rate Processes in Chemical Reaction Systems - Methods and Applications

Nucleophilic Reactivity of a Nitride-Bridged Diuranium(IV) Complex: CO2 and CS2 Functionalization

Atomic Scale Microstructure and Properties of Se-Deficient Two-Dimensional MoSe2