Publications associées à Chimiométrie

Hardware and Software Interfaces Design for Multi-Panel Electrochemical Sensors

The exponential growth of wearable healthcare devices market is fostered by the internetof- things (IoT) era. Connected smart biosensors enable a decentralized healthcare that does not constrain the user to be in a medical facility to get a real-time insig ...

EPFL2021

Model selection for partial least squares calibration and implications for analysis of atmospheric organic aerosol samples with mid-infrared spectroscopy

Satoshi Takahama

In developing partial least squares calibration models, selecting the number of latent variables used for their construction to minimize both model bias and model variance remains a challenge. Several metrics exist for incorporating these trade-offs, but t ...

Wiley-Blackwell2015

Ad Hoc Microphone Array Calibration: Euclidean Distance Matrix Completion Algorithm and Theoretical Guarantees

Hervé Bourlard, Philip Neil Garner, Afsaneh Asaei, Mohammadjavad Taghizadeh, Reza Parhizkar

This paper addresses the problem of ad hoc microphone array calibration where only partial information about the distances between the microphones is available. We construct a matrix consisting of the pairwise distances and propose to estimate the missing ...

2015

Subspace Correction Methods in Multivariate Calibration

Pamandeep Singh Gujral

Productivity, quality, safety, and environmental concerns have driven major advancements in the development of process analyzers. Analyzers generate measurement data that are useful for characterizing product and process attributes (key variables), thereby ...

EPFL2011

Framework for explicit drift correction in multivariate calibration models

Dominique Bonvin, Michael Amrhein, Pamandeep Singh Gujral

Latent-variable calibrations using principal component regression and partial least-squares regression are often compromised by drift such as systematic disturbances and offsets. This paper presents a two-step framework that facilitates the evaluation and ...

2010

Classification of magnetic resonance images from rabbit renal perfusion

Dominique Bonvin, Michael Amrhein, Pamandeep Singh Gujral

The feasibility of using chemometric techniques for the automatic detection of whether a rabbit kidney is pathological or not is studied. Sequential images of the kidney are acquired using Dynamic Contrast-Enhanced Magnetic Resonance Imaging with contrast ...

2009

Automatic detection of reaction start/endpoints in chemical and biotechnological reaction systems

Michael Amrhein, Simon Crelier

A classification methodology for the automatic detection of start- and endpoints of chemical and biotechnological reaction systems from spectral reaction data is proposed. In the calibration phase, several batch experiments must be conducted covering the e ...

2007

Assessing Dependences within Multivariate Time Series Partializing the Knowledge of Thirds

Oscar De Feo, Cristian Carmeli

A method to estimate from multivariate measurements the dependences within a network of coupled dynamical systems is proposed. The method is non-parametric and resorts to a statistics of the eigen-spectrums of the time series partial correlation matrices. ...

2006