Surface superhydrophobe

In chemistry and materials science, ultrahydrophobic (or superhydrophobic) surfaces are highly hydrophobic, i.e., extremely difficult to wet. The contact angles of a water droplet on an ultrahydrophobic material exceed 150°. This is also referred to as the lotus effect, after the superhydrophobic leaves of the lotus plant. A droplet striking these kinds of surfaces can fully rebound like an elastic ball. Interactions of bouncing drops can be further reduced using special superhydrophobic surfaces that promote symmetry breaking, pancake bouncing or waterbowl bouncing. In 1805, Thomas Young defined the contact angle θ by analysing the forces acting on a fluid droplet resting on a smooth solid surface surrounded by a gas. where = Interfacial tension between the solid and gas = Interfacial tension between the solid and liquid = Interfacial tension between the liquid and gas θ can be measured using a contact angle goniometer. Wenzel determined that when the liquid is in intimate contact with a microstructured surface, θ will change to θW* where r is the ratio of the actual area to the projected area. Wenzel's equation shows that microstructuring a surface amplifies the natural tendency of the surface. A hydrophobic surface (one that has an original contact angle greater than 90°) becomes more hydrophobic when microstructured – its new contact angle becomes greater than the original. However, a hydrophilic surface (one that has an original contact angle less than 90°) becomes more hydrophilic when microstructured – its new contact angle becomes less than the original. Cassie and Baxter found that if the liquid is suspended on the tops of microstructures, θ will change to θCB* where φ is the area fraction of the solid that touches the liquid. Liquid in the Cassie-Baxter state is more mobile than in the Wenzel state. It can be predicted whether the Wenzel or Cassie-Baxter state should exist by calculating the new contact angle with both equations. By a minimization of free energy argument, the relation that predicted the smaller new contact angle is the state most likely to exist.