Concept

Le Chatelier's principle

Publications associées (33)

On the Convergence to the Non-equilibrium Steady State of a Langevin Dynamics with Widely Separated Time Scales and Different Temperatures

Nicolas Macris, Emanuele Mingione, Diego Alberici

We study the solution of the two-temperature Fokker-Planck equation and rigorously analyse its convergence towards an explicit non-equilibrium stationary measure for long time and two widely separated time scales. The exponential rates of convergence are e ...

Cham2024

L’habitat minimal au sein des bureaux vacants

José Gabriel Silva

La Suisse attire de nouveaux habitants et la construction à neuf de logements ralentit car l’extraction massive de ressources naturelles n’est plus de mise. Les sphères politiques parlent alors d’une crise du logement qu’il est impératif de résoudre car le ...

2023

Enriching the Computational Toolbox for Organocatalysis

Simone Gallarati

Organocatalysis has evolved significantly over the last decades, becoming a pillar of synthetic chemistry, but traditional theoretical approaches based on quantum mechanical computations to investigate reaction mechanisms and provide rationalizations of ca ...

EPFL2023

Optimal enzyme utilization suggests that concentrations and thermodynamics determine binding mechanisms and enzyme saturations

Vassily Hatzimanikatis, Daniel Robert Weilandt, Asli Sahin

One of the main challenges hampering the development of kinetic models is the lack of kinetic parameters for many enzymatic reactions. Here, the authors introduce a framework to explore the catalytically optimal operating conditions of any complex enzyme m ...

NATURE PORTFOLIO2023

Effects of impurities and local behavior characterization using active thermography on solid oxide electrolysis cells

Guillaume Jeanmonod

Ambitious policies are needed from every country to drastically curtail the anthropogenic emission of greenhouse gases responsible for the on-going modification of the earth's climate. A quick transition towards a society fully based on renewable materials ...

EPFL2021

Fluctuation-dissipation relations in the absence of detailed balance: formalism and applications to active matter

Ignacio Pagonabarraga Mora, Sara Dal Cengio

We present a comprehensive study about the relationship between the way detailed balance is broken in non-equilibrium systems and the resulting violations of the fluctuation-dissipation theorem. Starting from stochastic dynamics with both odd and even vari ...

IOP PUBLISHING LTD2021

Efficient conversion of chemical energy into mechanical work by Hsp70 chaperones

Paolo De Los Rios, Alessandro Barducci, Salvatore Assenza, Alberto Stefano Sassi

Hsp70 molecular chaperones are abundant ATP-dependent nanomachines that actively reshape non-native, misfolded proteins and assist a wide variety of essential cellular processes. Here, we combine complementary theoretical approaches to elucidate the struct ...

2019

Protection contre les crues et renaturation de la Drance à Martigny - Du barrage filtrant de La Condémine au pont de Courvieux

Giovanni De Cesare

La Ville de Martigny en Valais a été victime à plusieurs reprises de débordements de la Drance, occasionnés par des débâcles glaciaires et des crues à fort charriage. Pour remédier à cette situation de risque important, un projet d’aménagement du cours d’e ...

2018

The underappreciated role of nonvolatile cations in aerosol ammonium-sulfate molar ratios

Athanasios Nenes, Hairun Guo

Overprediction of fine-particle ammonium-sulfate molar ratios (R) by thermodynamic models is suggested as evidence for interactions with organic constituents that inhibit the equilibration of gas-phase ammonia with aerosol sulfate and questions the equilib ...

2018

Exergy assessment of single and dual pressure industrial ammonia synthesis units

In exothermic, equilibrium-limited processes such as ammonia synthesis, higher per-pass conversions are often achieved by withdrawing the enthalpy of reaction before the conversion has been completed. However, although inter-bed cooling may help controllin ...

2017

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