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We introduce a family of elementary singularities that are point-Holder alpha-regular. These singularities are self-similar and are the Green functions of fractional derivative operators; i.e., by suitable fractional differentiation, one retrieves a Dirac ...
Institute of Electrical and Electronics Engineers2010
This article treats the problem of learning a dictionary providing sparse representations for a given signal class, via ℓ1-minimisation. The problem can also be seen as factorising a \ddim×\nsig matrix $Y=(y_1 \ldots y_\nsig), , y_n\in \R^\ ...
Institute of Electrical and Electronics Engineers2010
The isolation and characterisation of natural products remains a challenge in chemistry owing to nature's magnificent diversity. Natural products or natural product derivatives have always been used in traditional medicine to treat a variety of diseases. T ...
The photophysical characterization of three soluble derivatives of single-wall carbon nanotubes (SWCNTs), functionalized with poly(ethylene glycol) (PEG), co-functionalized with PEG and aminofluorene and co-functionalized with PEG and aminoanthracene is re ...
We report the total synthesis of a series of pyrrolizidine analogues of casuarine (1) and their 6-O-alpha-glucoside derivatives. The synthetic strategy is based on a totally regio- and stereoselective 1,3-dipolar cycloaddition of suitably substituted alken ...
The quantum instanton approximation is used to compute kinetic isotope effects for intramolecular hydrogen transfer in cis-1,3-pentadiene. Due to the importance of skeleton motions, this system with 13 atoms is a simple prototype for hydrogen transfer in e ...
Nostocarboline, a chlorinated and N-methylated carbolinium alkaloid, displays potent and selective inhibition of photoautotrophic organisms as well as the malaria parasite Plasmodium falciparum, while showing very low toxicity to bacterial and fungal patho ...
Over the last decade, several protein tags have been developed for the specific and covalent labeling of fusion proteins with small organic probes. Among them, SNAP-tag has been used in many applications such as live cell imaging, protein microarrays and t ...
We introduce an alternative approach to the first-principles calculation of NMR shielding tensors. These are obtained from the derivative of the orbital magnetization with respect to the application of a microscopic, localized magnetic dipole. The approach ...
The logarithmic layer of double-averaged (in time and space) streamwise velocity profiles obtained from field measurements made in the Swiss rivers, Venoge and Chamberonne is parameterized and discussed. Velocity measurements were made using a 3D Acoustic ...