Porteur de charge

Résumé

Un porteur de charge est, en sciences physiques, une particule ou une quasi-particule qui porte une charge électrique. En se déplaçant, les porteurs de charge créent un courant électrique, comme les ions dans les solutions liquides et les électrons dans les solides. En électronique cette notion est incontournable, les deux porteurs de charge considérés sont les électrons, portant une charge −e, les trous, peuvent se déplacer assez librement dans le réseau cristallin. Ils sont souvent représentés comme formant un nuage, et leur comportement peut être modélisé par celui d'un gaz de Fermi. Comme leurs électrons se déplacent uniformément en suivant le gradient de tension, les métaux conduisent le courant électrique. Les solutions ioniques conduisent l'électricité pour une raison similaire, les porteurs de charge sont également libres. Ce sont les cations et anions de la solution. Une solution d'eau pure est donc à température ambiante moins bonne conductrice qu'une solution salée qui con

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Chargement

Free carriers in nanocrystalline titanium dioxide thin films

Simon Springer

This thesis analyzes the properties of heavily doped nanocrystalline titanium dioxide. Thin films were deposited by magnetron sputtering with either water vapor as reactive gas or a periodically interrupted oxygen supply. The samples were at the same time electrically conducting and transparent. They consisted of mixtures of rutile, anatase and amorphous phases. Titanium dioxide is chemically stable, hard, non-toxic, transparent, and inexpensive. Due to a high refractive index it is often found in optical applications as a thin film coating. For many purposes it is interesting to take advantage of a combination of good transparency and electrical conductivity. An even larger field of applications would open if the electric conductivity of TiO2 could be increased in a controlled manner. Conventional bulk doping is limited, however, by low solubility limits. Highly conducting nanocrystalline TiO2 thin films have been obtained recently by sputtering in presence of water vapor. The present project intends to elucidate the doping mechanisms at work in such films. In addition, an alternative process to achieve grain-boundary doping of TiO2 was explored. Spectrophotometry over a wide spectral range (0.05 to 5 eV) was the main tool in probing the mobile electrical charge carriers. The interpretation of these optical measurements required appropriate models. The models developed took many structural properties into account, such as thickness, surface roughness, density, anisotropy and crystalline phase composition. The phase and morphology of the films were analyzed by X-ray diffraction and reflection, scanning probe microscopy, and electron microscopy. The chemical analyses included electron-probe microanalyses, Rutherford backscattering and elastic recoil detection analysis. The DC electrical properties were measured between room temperature and 250 °C. Most water-deposited samples showed semiconducting behavior with an activation energy of the order of 100 meV. The optical measurements revealed a broad absorption band around 1 eV. The absorption coefficient scaled with conductivity. It was successfully modelled as a Lorentzian. Similar absorption bands have been reported for reduced rutile and anatase single crystals. Water-deposited samples containing anatase exhibited a metallic behavior. In these samples the thermal activation energy was reduced to about 30 meV and the charge carriers displayed a high mobility (3 cm2V-1s-1). The infrared absorption band was about 10 times less important than in the samples devoid of anatase. Thin films of TiO2 intercalated with the equivalent of nanometer-thick layers of Ti were prepared. By changing the period in the oxygen supply the grain size, and thereby the film properties, could be modified. The films obtained in this way had many properties in common with water-deposited films. They showed the same absorption band in the infrared, had comparable charge carrier densities and were electrically conductive (102 to 104 Sm-1 at room temperature). To our knowledge, this was the first time that such high electrical conductivities were achieved by sputtering in an oxygen plasma.

EPFL2004

Chargement

Dynamics of Electronic and Ionic Charges in Cyanine Organic Semiconductor Devices

Sandra Christina Jenatsch

Organic semiconductor materials have been widely applied in optoelectronic devices to replace their inorganic counterparts and explore new fields of applications. Due to their high extinction coefficients, chemical tunability and solubility, cyanine dyes are an interesting class of molecules to be employed in organic semiconductor devices. Their beneficial properties have been demonstrated in organic solar cells (OSC), photodetectors and recently in organic light-emitting electrochemical cells (OLEC). The focus of this thesis is to analyse different aspects regarding the dynamics of electronic and ionic charges in cyanine based devices. Models and conclusions are not restricted to cyanine based devices but can potentially be applied in various systems where combined ionic and electronic charges are present. In order to focus on electronic processes in OSCs, a combination of steady-state, transient and impedance analysis is used. It is resolved that trapped charges can be introduced at the dye/hole extracting layer interface by using specific solvents for the cyanine layer fabrication. These measurements also reveal the low hole mobility of cyanine films which in turn limits the possible upper layer thickness in OSCs. A frequently used way to enhance the conductivity of organic semiconductors is the addition of extra charges by chemical doping. This concept is employed for a near-infrared absorbing dye which is used as donor in a bilayer solar cell. The dependence of all figures of merit versus doping concentration and layer thickness is studied in detail. It is found that the performance of the optimised cell is not further improved by doping, but that it presents a good option if thicker layers are required, e.g. on rough substrates. Furthermore, the stability and degradation pathway of the p-doped species is analysed. This information is of general relevance as they also occur after charge transfer at the heterojunction interface of an OSC and during operation of OLECs. The dynamics of ionic charge carriers is separated into two contributions. In a first step, the steady-state diffusion profile of the counter ion within a cyanine/fullerene bilayer structure is scrutinised using different profiling techniques. An unexpected constant ion profile is found throughout the C60 layer. Simultaneously, the potential within the acceptor is measured by the Kelvin probe technique. A mechanism of combined electron and ion transfer from the C60 to the dye and vice versa is proposed which is in agreement with the experimental results. A prerequisite for OLEC operation is the mobility of ionic charge carriers. Their dynamics in cyanine salts under the effect of an external field is therefore studied in such devices. Several methods are developed and applied to characterise the dynamic p-i-n structure in detail, i.e. the position and width of the intrinsic region as well as the doping concentrations in p- and n-doped regions. The combination of all these methods helps to understand the transient behaviour of these cyanine devices but can also be adapted to other OLEC systems. A major drawback of cyanine dyes as emissive material is their low fluorescence quantum yield in solid films. To overcome this restriction and improve the OLEC efficiency, host-guest systems with various visibly emitting dyes are studied. The gain in fluorescence quantum yield in the film can directly be transferred to an increase in external quantum efficiency of the device.

EPFL2017

Chargement

Organic photovoltaics (OPV) have the potential to provide low-cost solar-to-electricity converting devices. Improving such devices requires a deeper understanding of the ultrafast photoinduced processes occurring after light absorption. We have performed femtosecond (fs) transient absorption spectroscopy, as well as time-resolved electroabsorption (Stark effect) on model OPV systems to follow electron and hole transfer dynamics, as well as charge carrier motion in the active layer to the electrodes. Solid-state cyanine borate (Cy3-B) films undergo intra-ion pair reductive quenching on the picosecond (ps) timescale. We have found that when intermixing Cy3-B with a fullerene acceptor (PCBM), photoexcitation leads to the appearance of oxidized Cy3 in less than 70 fs. We correlated the rate and yield of Cy3 oxidation to the PCBM loading. We then investigated a cyanine Cy3-P in a bilayer geometry with fullerene C60. In this case, ultrafast electron transfer in less than 100 fs is followed by slower dissociation of interfacial charge transfer states in the presence of an electric field. A photoinduced Stark effect observed in neat C60 enabled to identify an initially delocalized excited state, which localizes in 360 fs. Lastly, we analyzed how microstructural changes in polymer pBTTT:PCBM blends impact free charge carrier formation and motion. We identified that the intermixed phase efficiently produces charge carriers within 100 fs, and that pure fullerene and pBTTT domains attract the charge carriers separating them further apart. This is ascribed to an energy cascade toward the neat domains. This thesis reveals ultrafast charge transfer at donor-acceptor interfaces in such OPV systems by means of fs transient absorption spectroscopy. Results emphasize that a second step is needed for charge separation in order to successfully compete with charge pair recombination in these systems. An electric field applied can act as a driving force to dissociate interfacial charge transfer states. Pure donor or acceptor domains attract holes or electrons, respectively, and reduce geminate charge recombination in blends. These second steps in charge separation were derived from photoinduced electroabsorption dynamics in transient absorption measurements, as well as time-resolved electroabsorption based on the Stark effect.

EPFL2015

Chargement

Dynamics of Electronic and Ionic Charges in Cyanine Organic Semiconductor Devices

Sandra Christina Jenatsch

EPFL2017

Free carriers in nanocrystalline titanium dioxide thin films

Simon Springer

EPFL2004

EPFL2015