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The aim of this thesis was to develop a new type of liquid-core capsules obtained by co-extrusion using the laminar jet break-up technique. These capsules, composed of an organic phase as the core and a hydrogel membrane, were meant to be applied as an in- ...
Some models of brain energy metabolism used to interpret in vivo (13)C nuclear magnetic resonance spectroscopic data assume that intramitochondrial alpha-ketoglutarate is in rapid isotopic equilibrium with total brain glutamate, most of which is cytosolic. ...
The present study examines the effect of humic acid on the uptake kinetics of Cd(II), Cu(II), and Pb(II) by the freshwater alga Chlorella kesslerii. The results demonstrated that the relative proportion of Pb in the cell wall layer is greater than that of ...
Hydrophilic/hydrophobic patterning is a well-established design strategy to guide secondary structure formation of both natural as well as non-natural oligomers and polymers. This contribution explores the feasibility of a new approach for the synthesis of ...
A new target in AIDS therapy development is HIV-1 integrase (IN). It was proven that HIV-1 IN required divalent metal cations to achieve phosphodiester bond cleavage of DNA. Accordingly, all newly investigated potent IN inhibitors contain chemical fragment ...
The relaxivity of commercially available gadolinium (Gd)-based contrast agents was studied for X-nuclei resonances with long intrinsic relaxation times ranging from 6 s to several hundred seconds. Omniscan in pure 13C formic acid had a relaxivity of 2.9 mM ...
The water-soluble complexes [{RuCl2(mTPPMS)(2)}(2)], [RuCl2(PTA)(4)], [RhCl(mTPPMS)(3)], [RhCl(mTPPTS)(3)], and [RhCl(PTA)(3)] (mTPPMS=sodium salt of meta-sulfonatophenyl-diphenylphosphine, mTPPTS=sodium salt oftris(meta-sulfonatophenyl) phosphine, and PTA ...
Novel organic sensitizers comprising donor; electron-conducting, and anchoring groups were engineered at molecular level and synthesized. The functionalized unsymmetrical organic sensitizers 3-{5-[N,N-Bis(9,9-dimethylfluorene-2-yl)phenyl]-thiophene-2-yl}-2 ...
C-linked disaccharide derivatives mimicking O-beta-D-galactopyranosyl-(1-->3)-D-galactopyranosides (end groups in Core-B structures of biologically important proteoglycans) have been obtained from isolevoglucosenone and beta-D-galactopyranosylcarbaldehyde ...
The soln. structure of the two intimate ion pairs present in soln. for [PtMe(h2-olefin)(a-diimine)]BF4 compds. (1-3, shown as I.BF4, R = Ph, 4-MeC6H4, 4-CF3C6H4) their relative abundance and the consequent thermodn. equil. parameters were detd. by a quant. ...