Structure and Bonding of Isoleptic Coinage Metal (Cu, Ag, Au) Dimethylaminonitrenes in the Gas Phase
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CO adsorption on Pd atoms deposited on MgO(100) thin films has been studied by means of thermal desorption (TDS) and Fourier transform infrared (FTIR) spectroscopies. CO desorbs from the adsorbed Pd atoms at a temperature of about 250 K, which corresponds ...
Using the technique of double-resonance overtone photofragment spectroscopy (DROPS), we have measured rotationally resolved vibrational overtone transitions to the previously unobserved 5v(1), 6v(1), and 7v(1) levels of gas-phase trans-nitrous acid (HONO) ...
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Reactions of metalated nucleophiles M(I)Y [Y = OR, SR, NR2, PR2, AsR2, CR3, Si(SiMe3)3, R = organyl, H] with bis(2,2,6,6-tetramethylpiperidino)aluminum halides [tmp2AlX, (X = Cl, Br, I)] offer facile access to a variety of bis(amino)alanes of the type tmp2 ...
The reaction between the hydroxyl radical and the nitrogen dioxide radical in the gas phase has been studied with ab initio mol. dynamics simulations based on d. functional theory. Nitric acid HONO2 and cis-cis peroxynitrous acid ONOOH are formed spontaneo ...
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Methods and app. to study biol. mols. or biol. components at or in self-assembled monolayers (SAMs) on metal surfaces such as gold in aq. environments using attenuated total internal reflection Fourier transform infra-red (ATR-FTIR) spectroscopy are descri ...
(Ecole Polytechnique Federale de Lausanne, Switz.).1999
Infrared (IR) absorption spectroscopy and mass spectrometry have been simultaneously applied to dusty radiofrequency (RF) plasmas in methane, acetylene and ethylene. The combination of IR absorption spectroscopy and mass spectrometry allows the chemical co ...
The influence of the adipose tissue thickness on near-infrared spectroscopy to monitor the haemodynamics in muscles is investigated. It is shown by calculation of the mean optical pathlength of two-layered turbid media that the validity of the modified Bee ...