Deuterium separation and infrared photochemistry in chlorodifluoromethane (CF2HCl)
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The ruthenium(II) hexaaqua complex [Ru(H2O)6]2+ reacts with dihydrogen under pressure to give the h2-dihydrogen ruthenium(II) pentaaqua complex [Ru(H2)(H2O)5]2+.The complex was characterized by 1H, 2H and 17O NMR: d H = -7.65 ppm, J HD = 31.2 Hz, d O = -80 ...
The design, properties and optimization of an ultrasonic actuator are presented. Numerical modeling has been carried out and simulations with the FEM Ansys software have been realized. To avoid performing a large number of simulations, input parameters lik ...
With a view towards developing a method for molecular laser isotope separation (MLIS) of carbon, silicon and nitrogen, this work investigated the overtone pre-excitation - infrared multiple photon dissociation (OP-IRMPD) of CF3H, SiHCl3 and NH3. The study ...
High-pressure scanning tunneling microscopy was used to study the room-temperature adsorption of CO on a Pt(111) single-crystal surface in equilibrium with the gas phase. The coverage was found to vary continuously, and over the entire range from 10(-6)-76 ...
Melting experiments at high-pressure and temperature were conducted at pressures from 16 to 25 GPa using chondritic starting material but with slightly enhanced Na- and K-contents while keeping the chondritic Na/K ratio constant. The experiments revealed t ...
J. V. Kadam, W. Marquardt Lehrstuhl für Prozesstechnik, RWTH Aachen University, Turmstr. 46, 52064 Aachen, Germany B. Srinivasan, D. Bonvin Laboratoire d’Automatique, École Polytechnique Fédérale de Lausanne, CH-1015 Lausanne, Switzerland Optimization of T ...
An application to antenna optimization of bayesian network density of probability estimators is presented. This technique is very usefull for optimizations where abig number of parameters, multiple solutions and local minima increase the likelihood to conv ...
This study focuses on an interesting and important phenomenon that was employed in a new approach to laser isotope separation that has been recently proposed and developed in our laboratory for highly selective separation of carbon isotopes. This approach ...
We have further developed our recently reported two-laser technique for highly selective molecular isotope separation of carbon-13 [Boyarkin, Kowalczyk, and Rizzo, J. Chem. Phys. 118, 93 (2003)] with the objective of increasing the yield. An essential feat ...
An application to antenna optimization of bayesian network density of probability estimators is presented. This technique is very usefull for optimizations where abig number of parameters, multiple solutions and local minima increase the likelihood to conv ...