Total Synthesis of Cyrneine A

Karl Gademann, Cindy Fellay
2012
Article

Résumé

The tricyclic diterpene cyrneine A featuring a hexatrienal unit was prepared synthetically for the first time by a Heck reaction, a carbene ring expansion, and a reductive carbonylation. The structure of the natural product was assigned by X‐ray crystal analysis of a synthetic sample.

Source officielle

https://infoscience.epfl.ch/record/177265?ln=fr

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Total Synthesis of Cyrneine A

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