Thermo-economic optimization of a Solid Oxide Fuel Cell - Gas Turbine system fuelled with gasified lignocellulosic biomass

Within the context of sustainable energy supply and CO2 emissions reduction a Solid Oxide Fuel Cell (SOFC) - Gas Turbine hybrid system, fuelled with gasified woody biomass for medium scale applications (8MWth,BM of dry biomass) is studied in detail. The system consists of an air dryer moisture removal unit, a gasifier, a hot cleaning section made of a particulate removal unit (cyclone and candle filter) and a two-stage TAR removal unit, a SOFC and a gas turbine with optional CO2 capture. This modern technology has the advantage of using a renewable and CO2-neutral source and to be economically competitive at medium scales. The competitiveness of different process options is systematically compared by applying a coherent approach combining flowsheeting, energy integration and economic evaluation in a multi-objective optimization framework. This analysis reveals the importance of process integration maximising the heat recovery and valorising the waste heat, by cogeneration for example. The studied process options include indirect circulating fluidized bed (using steam or oxygen as gasification agent) and Viking gasifier, atmospheric or pressurized systems and optional pre-reforming in the hot gas cleaning. To close the thermal energy balance, a fraction of the produced syngas can be burnt. The energy integration results reveal that the steam production for the gasification and reforming are key parameters (S/B and S/C ratio) defining the process performance. A multi-objective optimization maximizing the efficiency and minimizing the capital investment costs is performed with respect to the operating conditions and the process configuration in order to assess the trade-offs and identify optimal process designs. The analysis shows the potential of the system converting woody biomass into electricity with energy efficiency greater than 70%.

Optimal process design for thermochemical production of fuels from biomass

Martin Gassner, François Maréchal

Transport applications are a major global source of greenhouse gas emissions and the production of fuels that are renewable and neutral in CO2 is an important issue in chemical process research and development. Contrary to the biological routes that produce bioethanol and -diesel on industrial scale through fermentation or esterification, 2nd generation biofuels obtained through thermochemical processing of lignocellulosic and waste biomass by means of gasification and fuel reforming are expected to be truly sustainable since high conversion efficiencies and a decidedly positive environmental balance are achieved. The poster addresses the optimal design of such thermochemical fuel production processes with respect to its environomic (energetic, economic and environmental) performance. Thereby, the challenge is to develop design methodologies that allow the identification of the most promising conversion routes in a specific environmental and economical context. Thermo-economic process modelling and integration techniques are coupled with a multi-objective optimisation algorithm to target the best process technology and operating conditions for the trigeneration of fuels, heat and power. The approach is demonstrated on the production of synthetic natural gas from wood considering different gasification technologies and the possibility to increase the fuel yield from biomass and electrical power by integrating an electrolyser in the system.

2008

Selected pathways for a more efficient conversion of biomass in cogeneration or fuel production

Daniel Favrat, Martin Gassner, Stefan Heyne, François Maréchal, Jan Van Herle

Among renewable energy sources biomass plays a major role. Several paths for improving the conversion of biomass with minimum burden on the environment are being pursued worldwide. This paper reviews some of the most recent results from research at the Swiss Federal Institute of Technology of Lausanne. On the theoretical and experimental sides it covers the improvement of biogas combustion engines using combustion prechambers both with spark ignition or autoignition in order to reduce the emissions while keeping a high efficiency level, the integration of ORC heat recovery cycles on biogas cogeneration engines and tests with real biogas in Solid Oxide planar Fuel Cells. On the process modelling side the paper reviews the environomic (environment, economic and energetic) optimisation of the design of biofuel production by means of gasification and fuel reforming. Thermo-economic process modelling and integration techniques are coupled with a multi-objective optimisation algorithm to target the best process technology and operating conditions for the trigeneration of fuels, heat and power.

2007

Optimal process design for thermochemical biofuel production plants

Daniel Favrat, Martin Gassner, François Maréchal

2007