Modular synthesis of supramolecular ureidopyrimidinone–peptide conjugates using an oxime ligation strategy
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Up to now, only a few collective or modular robot systems have proven capable of letting separate and autonomous units, or groups of units, self-assemble. In each case, ad hoc control algorithms have been developed. The aim of this paper is to show that a ...
The condensation of aryl boronic acids with 2,3-dihydroxypyridine gives boronates, which self-assemble to form tetrameric macrocycles as evidenced by X-ray crystallographic analyses. ...
This article illustrates the methods and results of two sets of experiments in which a group of mobile robots, called s-bots, are required to physically connect to each other, that is, to self-assemble, to cope with environmental conditions that prevent th ...
This paper discusses the solid state and melt nanoscale structure of a series of novel poly(ethylene glycol) (PEG) hybrid di- and triblock copolymers, which contain amphiphilic β-strand peptide sequences. The block copolymers have been prepared via solid-p ...
In this paper we introduce a new robotic system, called swarm-bot. The system consists of a swarm of mobile robots with the ability to connect to/disconnect from each other to self-assemble into different kinds of structures. First, we describe our vision ...
TThe synthesis and properties of a novel set of building blocks for the preparation of self-assembling biomaterials are described. These molecules consist of a relatively short oligo(L-lactic acid)n segment (n̄ = 10-40) that is substituted with a cholester ...
This report describes the synthesis and supramolecular organization of a novel class of linear-dendritic block copolymers. The molecules, which are termed rodcoil dendrons, consist of a cholesterol moiety that is attached to L-lysine dendrons of three diff ...
We present a new robotic concept, called SWARM-BOT, based on a swarm of small and simple autonomous mobile robots called S-BOTs. S-BOTs have a particular assembling capability that allows them to connect physically to other S-BOTs and form a bigger robot e ...
The outer membrane protein OmpF from Escherichia coli is a member of a large family of b-barrel membrane proteins. Some, like OmpF, are pore-forming proteins while others are active transporters or enzymes. We have previously shown that the receptor-bindin ...
There is considerable interest in synthetic ionophores with high affinity and selectivity for Li+. But so far, compounds that selectively bind Li+ in the presence of other alkali and alkaline earth metal ions are rare and current approaches toward this goa ...