Global Identification of Kinetic Parameters via the Extent-based Incremental Approach
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A new phosphoramidite ligand was used in the iridium-catalyzed allylic substitution reaction. This permitted high regio- and enantioselectivity on a wide variety of substrates and nucleophiles. Because of the stereospecificity of the reaction obtained by u ...
In this paper, we present a novel technique for calibrating central omnidirectional cameras. The proposed procedure is very fast and completely automatic, as the user is only asked to collect a few images of a checker board, and click on its corner points. ...
In this paper, we present a flexible new technique for single-viewpoint omnidirectional camera calibration. The proposed method only re-quires the camera to observe a planar pattern shown at a few different orienta-tions. Either the camera or the planar pa ...
A model for planar solid oxide fuel cell repeat elements and stacks has been developed. Distribution of concentrations, reaction rates and temperatures (both gases and solids) are computed as well as overall performance results. Specific experiments provid ...
The present thesis work provides new insight into the generation of allylmetal species and into their reactivity toward electrophiles. endo-Allylpotassiums are known to be more stable than their corresponding exo-isomers. The ring strain of methylenecycloa ...
The degrdn. of herbicides 4-chlorophenoxyacetic acid (4-CPA), 4-chloro-2-methylphenoxyacetic acid (MCPA), 2,4-dichlorophenoxyacetic acid (2,4-D) and 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) in aq. medium of pH 3.0 was comparatively studied by anodic oxi ...
Quinodimethanes are highly reactive toward dienophiles since Diels-Alder cycloaddn. results in an arom. product. D. functional-based 13C, 1H NMR, NICS, and MO-NICS calcns. indicate that the increase of arom. character of the developing benzenoid ring along ...
We derive a nonlinear stabilized Galerkin approximation of the Laplace operator for which we prove a discrete maximum principle on arbitrary meshes and for arbitrary space dimension without resorting to the well-known acute condition or generalizations the ...
This thesis presents the development of models for the simulation and optimization of the design of a planar solid oxide fuel cell (SOFC) stack. Fuel cells produce electric power directly from a fuel by electrochemical reactions. The high efficiencies demo ...
The gasification reaction of fir charcoal with CO2 was studied by isothermal thermogravimetric analysis under kinetic control. The derived reaction rate (r = dX/dt) as a function of the converted carbon mass (X) was compared with random pore model predicti ...