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Pronounced anisotropy of magnetic properties and complex magnetic order of a new oxi-halide compound Co-7(TeO3)(4)Br-6 has been investigated by powder and single-crystal neutron-diffraction, magnetization, and ac susceptibility techniques. Anisotropy of su ...
We report a comprehensive study of transport, magnetotransport, and magnetic properties of single crystals of BaVSe3. The paramagnetic metal-ferromagnetic metal transition at 43 K was followed as a function of pressure by measuring the electrical resistivi ...
Coordination assemblies formed by metal(II) dithiocarbamates M-II(R(2)dtc)2 (M = Zn, Cd, Hg, Mn, and Fe; R = Me, Et, iPr, nPr, and nBu) and nitrogen-containing ligands (L = DABCO, DMP, and HMTA) are shown to be sterically well consistent with the spherical ...
This review commences with a survey of the general synthetic routes leading to aminophosphines containing the P-NH subgroup. Recent examples involving functionalised and chiral aminophosphines are included. The synthesis and structural properties of deprot ...
This thesis reports results on magnetic properties of supported cobalt nanostructures. The nanostructures were grown on single crystal metal surface by Molecular Beam Epitaxy in an Ultra High Vacuum chamber. Our experimental setup is based on two in situ m ...
This thesis is concerned with supramolecular architectures assembled at metal surfaces. The investigations pursued two objectives. On the one hand, the focus was placed on the fabrication of low-dimensional surface-supported network structures by applying ...
Planar tetracoordinate carbons (ptC's) can be stabilized by four-membered ring perimeters composed of four bare transition metal atoms. DFT analyses of the MOs, electronic structures, energies, and magnetic properties of these CM4 species (where M represen ...
We report on the magnetic properties of two-dimensional Co nanoparticles arranged in macroscopically phase-coherent superlattices created by self-assembly on Au(788). Our particles have a density of 26 Tera/in(2) (1 Tera=10(12)), are monodomain, and have u ...
We have studied the evolution of the magnetic properties of monolayer-high cobalt islands on a Pt(111) surface as function of their exposure to oxygen. We observe a sequential quenching of magnetic anisotropy and magnetic moment. For minute exposures to ox ...
A review with 111 refs. presenting exptl. aspects of metal-cluster work including: supersonic- mol.- beam technol.; laser spectroscopy; mass spectroscopy; and low- and high-temp. matrix-isolation expts. The exptl. results discussed include: stability of cl ...