Investigation of the heterogeneously catalysed gas phase CO2 hydrogenation reaction: Development of analysis methods and
reaction analysis on pristine metal catalysts
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The present thesis work deals with the investigation of the heterogeneous reactions involving nitrate radical (NO3), dinitrogen pentoxide (N2O5) and ozone (O3) on surrogates of atmospheric mineral dust particles characteristic of the troposphere. An additi ...
The main objectives of this work are 2-fold : The development of a novel type of composite material based on carbon nanofibers supported on sintered metal fibers filters (CNF/SMF) and to explore the use of this material as a catalytic support for a model r ...
The ruthenium(II) hexaaqua complex [Ru(H2O)6]2+ reacts with dihydrogen under pressure to give the h2-dihydrogen ruthenium(II) pentaaqua complex [Ru(H2)(H2O)5]2+.The complex was characterized by 1H, 2H and 17O NMR: d H = -7.65 ppm, J HD = 31.2 Hz, d O = -80 ...
Density functional theory is employed to investigate atomic layer deposition mechanism of HfO2, on Ge(I 0 0)-2 x I surface. Both the HfCl4 and H2O half-reactions proceed through an analogous trapping-mediated mechanism. The neighboring hydroxyl in the reac ...
The water-sol. ruthenium(II) complexes [Cp'RuX(PTA)2]Y and [CpRuCl(PPh3)(mPTA)]OTf (Cp' = Cp, Cp*, X = Cl and Y = nil; or X = MeCN and Y = PF6; PTA = 1,3,5-triaza-7-phosphaadamantane; mPTA = 1-methyl-1,3,5-triaza-7-phosphaadamantane) were used as catalyst ...
The photo-curing behavior of reactive blends of dipentaerythritol penta/hexaacrylate (DPHA) with an acrylated hyperbranched polyester and an acrylated hyperbranched polyether was investigated by means of photo differential scanning calorimetry. The chemica ...
Investigations of spectrum adjustment by unfolding techniques for different locations of critical and driven subcritical MUSE4 configurations are presented. The current analysis is based on the recent accomplishment of specific foil activation measurements ...
Initial surface reaction mechanism for atomic layer deposition of HfO2 on the hydroxylated GaAs(001)-4x2 surface using HfCl4 and H2O as precursors is investigated using hybrid density functional theory. The reaction between HfCl4 and H2O with the hydroxyla ...
Cluster calculations employing hybrid density functional theory have been carried out to examine the initial surface reactions in atomic layer deposition (ALD) of TiN thin films on the SiO2 surface using TiCl4 and NH3 as precursors. The potential energy su ...
Effects of channel bowing on the pin power and 238U capture rate distributions have been studied experimentally and analytically in a test zone consisting of 9 full-size Westinghouse Atom SVEA-96+ fuel assemblies in the PRO-TEUS critical facility. A very s ...