Publication
Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
Publications associées (40)
Estrogenic, Genotoxic, and Antibacterial Effects of Chemicals from Cryogenically Milled Tire Tread
Kristin Schirmer, Florian Frédéric Vincent Breider, Benoît Jean Dominique Ferrari, Thibault Béranger Masset
Tire and road wear particles (TRWP) contain complex mixtures of chemicals and release them to the environment,and potential toxic effects of these chemicals still need to be characterized. We used a standardized surrogate for TRWP,cryogenically milled tire ...
2024The simultaneous Selective Catalytic Reduction of N2O and NO over Fe-exchanged zeolites
Iron-exchanged zeolites are industrial heterogeneous catalysts deployed to remediate anthropogenic emissions of both nitrous oxide (N2O) and nitrogen oxides (NOx = NO + NO2). Despite the extensive scientific attention received, limited knowledge is availab ...
EPFL2024An Overview of Heterogeneous Catalysts Based on Hypercrosslinked Polystyrene for the Synthesis and Transformation of Platform Chemicals Derived from Biomass
Platform chemicals, also known as chemical building blocks, are substances that serve as starting materials for the synthesis of various value-added products, which find a wide range of applications. These chemicals are the key ingredients for many fine an ...
Basel2023Tuning the reactivity of uranium towards small molecules in multimetallic complexes
One of the main goals of organometallic chemistry in the last decades was the activation of small molecule in mild reaction conditions. Even though multiple examples of catalytic cycles able to produce fine chemicals from cheap and abundant sources using t ...
EPFL2023Lignin Hydrogenolysis: Phenolic Monomers from Lignin and Associated Phenolates across Plant Clades
The chemical complexity of lignin remains a major challengeforlignin valorization into commodity and fine chemicals. A knowledgeof the lignin features that favor its valorization and which plantsproduce such lignins can be used in plant selection or to eng ...
AMER CHEMICAL SOC2023Hydro-processing of biomass using novel metal-organic framework (MOF)/polymer composite catalysts
Generating value, in the form of functional chemicals, from biomass is a critical need of today. It is expected that replacing petroleum with biomass as the source of many commodity and fine chemicals can lead the transition away from a fossil-fuel based e ...
EPFL2022Well-Defined Copper-Based Nanocatalysts for Selective Electrochemical Reduction of CO2 to Ethylene and Ethanol
Raffaella Buonsanti, Ludovic Emile Frédy Zaza, Kevin Rossi
The electrochemical CO2 reduction reaction (CO2RR) holds the promise to revolutionize the chemical industry by producing value-added chemicals and fuels from CO2 and water while storing renewable energy. However, catalyst design still remains one of the ma ...
2022Data-Driven Advancement of Homogeneous Nickel Catalyst Activity for Aryl Ether Cleavage
Matthew Wodrich, Benjamin André René Meyer, Manuel Cordova, Boodsarin Sawatlon
The increasing urgency to make chemical processes more environmentally friendly while continuing to derive the chemicals required for modern society from renewable resources requires the development of a forthcoming generation of synthetic processes and th ...
AMER CHEMICAL SOC2020Acceptorless dehydrogenation and hydrogenation of N- and O-containing compounds on Pd3Au1(111) facets
Paul Joseph Dyson, Zhaofu Fei, Antoine Philippe Van Muyden, Zhangjun Huang, Xinjiang Cui, Tao Wang
Catalytic dehydrogenation and hydrogenation of amines and alcohols are important in the synthesis of fine chemicals. Despite several efficient homogeneous catalysts having been identified, highly active heterogeneous catalysts remain elusive, although they ...
2020CO2 chemical transformations using metal-organic frameworks
During the last decades, intensive efforts have been applied to tackle the enormous emissions of CO2 into atmosphere. These efforts include not only developing efficient carbon capture techniques, but also the introduction of new ways to transform the capt ...
EPFL2020