Third-Generation Solar Cells: Toxicity and Risk of Exposure

Solar energy is considered clean energy, and its use is predicted to increase in the near future. Most installed units today are crystalline solar cells, but the field is in constant development, and when the first dye sensitized solar cell was published byGratzelandO'Reagana new, third-generation, solar power was born. Highly toxic metals are used to produce the photovoltaic units today, and with the predicted increase in solar cell installation, the human health hazards of these panels could become an issue. Additionally, many of these materials are used in their nanoform, which is associated with an additional risk. In this article, we discuss the technology behind the third-generation solar cells with its valuable use of nanotechnology as well as the possible health hazard when such nanomaterials are used in solar power units. We will show that the main exposure will occur either during the development and production phases or at the end-of-life stage of the solar cells, where toxic material can leach into landfills, and subsequently into the environment and impact the ecosystem directly, or humans indirectly through edible plants or drinking water.

Optimisation of Urban Form by the Evaluation of the Solar Potential

Marylène Montavon

What will the cities of tomorrow look like? This is a crucial question because in the four and a half billion years of its existence, the Earth has never been so threatened, as it is today. Since 2008 half of the world's population has lived in towns – more than 70% in rich nations. Three quarters of CO2 emissions are produced in towns, 75% of the world's energy is consumed in towns. The battle for our climate, for the continuation of our species and all other life, will be largely waged in cities. Will it be possible to create the ideal ecological town? The objective of this study is to compare actual and theoretical urban forms in order to explore the diverse effects of daylighting and solar potential on densely built-up sites. Indeed, the search for ideal solar orientations has been a persistent problem from the 19th century until the beginning of the 20th. Even today, for all our scientific knowledge and empirical experience of solar energy, making the correct choice has still not crossed the boundary from an enigmatic, tricky art into the field of an exact science. As a first step, six existing urban sites in Switzerland and Brazil, as well as two projects in the United Kingdom, a few generic models and a utopian city, were modelled and analyzed. The goal was not merely the construction of new, exemplary districts but also the transformation of existing towns. The findings have been used to assess the potential of façades and roofs located in urban areas for active and passive solar heating, photovoltaic electricity generation and daylighting. The results obtained from these different case studies revealed large variations of the potential for solar energy collection on the buildings' façades and roofs. Ideally, these investigations are expected to help architects and town planners understand how to optimise solar collection on buildings design. In addition, a study was made of the Contemporary City of Three Million Inhabitants created by Le Corbusier. According to the latter, the Contemporary City could increase the urban capacity and at the same time improve the urban environment and the efficiency of the city. Therefore the present study extracted the solar potential of this utopian city in order to assess Le Corbusier's propositions. Since 1922, Le Corbusier's studies have influenced architects and town-planners in their choice of orientations and urban forms: it was therefore crucial to discover if this reliance on Le Corbusier was justified. Solar irradiation and illuminance values obtained through numerical simulations form the core part of the method. The method adopted for the entire set of computer simulations consisted in modelling — via a computer-aided drawing piece of software, namely AutoCAD — the digital model of each building or group of buildings prior to exporting them to an urban performance analysis software (PPF/RADIANCE software package). Spatial distributions of solar irradiation and daylight fluxes over the overall building façades and roofs were calculated using ray-tracing simulation techniques to determine the appropriate placement of different solar technologies (passive and active solar, photovoltaic and daylighting). Performance indicators were used to assess the solar utilisation potential of the urban sites (e.g. statistics of sky view factors and daylight factors) in order to determine the optimal solar strategies for a given urban context. In addition, various works and sun-related recommendations that have appeared mainly since the end of the nineteenth century, together with the various scientific models and software tools pertaining to this topic, are presented in this study.

EPFL2010

Computational Modeling of Thin-Film Silicon Solar Cells and Modules

Thomas Andreas Lanz

Solar photovoltaic energy production relies on the direct conversion of sunlight into electricity. Silicon thin-film solar cells represent a reliable and environmentally friendly technology to make photovoltaics economically viable. As these solar cells do not contain any rare or toxic materials they are an ideal candidate for the large scale deployment of solar energy. At the same time photovoltaic energy production is ideal for off-grid, stand-alone installations. This thesis presents new methods and results on computational engineering of thin-film silicon solar cells and modules. Computational engineering employs numerical methods and simulation techniques to address engineering challenges. Predictive numerical simulations allow for device optimizations that otherwise require substantial experimental effort and they may lead to new insights into the device physics which is the basis for further improvements in terms of cell efficiency and lifetime. We discuss the development of two new simulation methods and present several case studies that illustrate their use in solar cell characterization and optimization. The first presented method addresses optical simulations, i.e. the interaction of the solar cell with sunlight. Our optical model is based on the net-radiation method that considers incoherent, ray-like propagation of light. We extend the net-radiation method with thin-film optics to allow for arbitrary sequences of thick and thin layers. Experimentally, advanced techniques such as optimized surface textures have been developed to increase the absorption in the solar cell and thereby to increase the produced current. We illustrate how our optical model takes into account these textures by means of azimuth integrated light scattering properties to formulate a computationally efficient model of light propagation within the solar cell. Our optical model thus integrates coherent and incoherent propagation of light as well as a non-iterative treatment of ligth scattering. It bridges the gap between wave and ray optics that alternative approaches are most often facing. We first apply the method to study a recently proposed rear electrode architecture based on lithium fluoride and aluminum in amorphous silicon solar cells. Our model-based optical analysis identifies the increased reflectivity of this back electrode as its main advantage. Secondly, we then explore the potential performance gains in microcrystalline silicon solar cells that can be reached by eliminating absorption in layers that do not contribute to the photogeneration of solar cell current. Finally, our optical model is also suited for other solar cell technologies and we illustrate its extension and application to light extraction calculations in light emitting diodes (LEDs). Our optical model has been incorporated into the software package setfos, commercialized by Fluxim Inc. It is thus available to the research community. We then turn to address large area solar modules. A new method based on the finite element method (FEM) is presented to calculate the electrical charge and heat transport in these devices and how it is influenced by defects as well as partial shading. We identify such defects with surface temperature measurements by means of lock-in thermography and demonstrate how our model accounts for the thermal signature of localized defects. Taking into account the large aspect ratio of thin-film solar modules we show how geometrical projections can be used to reduce the model complexity, leading to a numerically efficient approach based on the finite element method. We demonstrate this by presenting full current-voltage curves of solar modules under partial shading.

EPFL2013

Material Development for Perovskite/Silicon Tandem Photovoltaics

Peter Joseph Fiala

The developed world is built on the fact that energy is readily available and functionally infinite. The electricity from the wall, the gas at the station, and the heat in our homes are reliable and low-cost. But this comfort is so far only possible through the combustion of fossilized carbon sources. This is not a sustainable system. Not only are these sources finite, but the long-term effects of this much combustion are catastrophic for our planet and species. Transitioning from current energy production to sustainable sources will require the development and deployment of a diverse group of technologies. Chief among these is the generation of electricity from sunlight, or photovoltaics (PV).Most modern PV is based on crystalline silicon. Silicon PV alone could be scaled to provide the necessary energy production, but this could be realized more quickly and efficiently if more advanced technologies are used. The defining metric is the cost per generated electricity. In the case of silicon, the current cost breakdown of materials, manufacturing, installation, and system costs leaves little room for further price reduction; and light-to-electricity efficiencies are near their practical limit. Of the proposed alternatives, the pairing of silicon with a thin film of lead-halide perovskite in a multijunction or "tandem" architecture is one of the most promising. This splits the solar spectrum in two, and raises the theoretical maximum efficiency from 33.3% to 45.1% based on each material better using its segment than any one material could use the full spectrum. The central goal of this thesis was therefore to advance the capability of this type of solar cell while remaining within the constraints of industrially-plausible production methods.Towards this goal, we first isolated perovskite layers to study what limits their performance. This led to improvements in the bulk material quality, the interfaces with adjacent materials, and the layer morphology. We reduced bulk disorder via balancing the annealing temperature, time, and environment. The interfaces were improved by selecting passivating materials which were compatible with our deposition methods. We further observed a complex interplay between the materials used and the environment of the annealing, which illuminated critical dependencies of device performance and gave us a more complete understanding of our material. Finally the morphology was improved via high-temperature annealing. This was enabled by a surface-binding additive which reduced the detrimental effects of such an anneal while preserving the benefits, resulting in a perovskite with less internal resistance. From there, we moved outside of the perovskite layer and developed a light scattering ZnO layer which increased the optical performance and absorption of our cells. Returning to the main goal of the thesis, the lessons learned from work on isolated perovskites were applied in tandems on textured silicon. We additionally increased the perovskite layer thickness and made the bottom-cell more robust to processing damages. Together, the result was a stabilized efficiency of 27.3%. This is better than any silicon cell to date, but work remains to achieve 30% and beyond, extend material stability, scale up the deposition area, and transfer these capabilities to industry. Together, the work done as a part of this thesis represents a step forward in the journey towards carbon-neutral energy production.

EPFL2022