Molecular Volcano Plots: Tools for Rationalizing and Predicting the Performance of Homogeneous Catalysts
Graph Chatbot
Chattez avec Graph Search
Posez n’importe quelle question sur les cours, conférences, exercices, recherches, actualités, etc. de l’EPFL ou essayez les exemples de questions ci-dessous.
AVERTISSEMENT : Le chatbot Graph n'est pas programmé pour fournir des réponses explicites ou catégoriques à vos questions. Il transforme plutôt vos questions en demandes API qui sont distribuées aux différents services informatiques officiellement administrés par l'EPFL. Son but est uniquement de collecter et de recommander des références pertinentes à des contenus que vous pouvez explorer pour vous aider à répondre à vos questions.
Metal complexes bearing phosphine ligands are attracting increasing attention for their applications in medicinal chem. In particular, organometallic ruthenium-phosphine complexes have been found to exhibit promising antitumor activity. The synthesis, anti ...
In light of the already proven applications of transition-metal (TM) oxide clusters, including catalysis, selective sorption, sepns., mol. recognition, environmental decontamination, and nanotechnol., one can imagine that the development of framework mater ...
Supported metal catalysts are important from both an industrial and a scientific point of view. They are used, amongst others, in large-scale processes such as catalytic reforming, hydrotreating, polymerization reactions and hydrogenations. Often, these ca ...
Diffusion of carbon is the crucial step in chemical vapor deposition (CVD) growth of carbon nanotubes (CNTs) On metal nanoparticles. Using first principles techniques we model the binding and diffusion of carbon atoms and dimers on late transition (Ni, Pd, ...
Hybrid solids, made of chem. dissimilar components, have drawn much interest in advanced materials synthesis due to their structural versatility and multifunctional properties. For example, metal-org. frameworks (MOFs) have been extensively explored for th ...
The β-diketiminate class of ligands is renowned for the stabilization of coordinatively unsatd. main-group and transition metal complexes. Moreover, the application and scope of transition metal β-diketiminate complexes in the catalytic transformation of o ...
A series of ruthenium(II) N-heterocyclic carbene chelate complexes were prepd. by using bidentate chelating alkene-carbene, thioether-carbene, carboxylate-carbene and bis-carbene ligands. Metalation of 1-R-3-X-imidazolium salts (1-3, R = Me, X = allyl, MeS ...
A novel approach based on the Stober method allows breaking of the symmetry of core-shell systems based on metallic core and metal oxide shell. By adjusting the proportion of the TiO2 precursor with regard to the silica precursor, different morphologies of ...
Control over the structure of metals at the mesoscale (2-50 nm) is crucial for emerging applications such as energy conversion, sensing, and information processing. The self-assembly of nanoparticles with block copolymers provides a natural entry point to ...
Trace metal speciation in seawater from the Bulgarian Black Sea coast was studied in situ by hollow fiber permeation liquid membrane (HF-PLM) and by diffusion gradients in thin- film gels (DGT). The concentrations of Cd, Cu, Ni, and Pb determined by HF- ...