Organic Chemistry and Synthesis Rely More and More upon Catalysts
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Recent years have seen spectacular developments in the domain of nano-optics.
Alongside the well-known techniques of super-resolution microscopy progress
in nanofabrication has enabled important improvements in the fields
of optical imaging and spectros ...
EPFL2020
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The creation of new chiral ligands capable of providing high stereocontrol in metal-catalyzed reactions is crucial in modern organic synthesis. The production of bioactive molecules as single enantiomers is increasingly required, and asymmetric catalysis w ...
WILEY-V C H VERLAG GMBH2020
Particulate matter (PM) pollution causes adverse health effects and millions of deaths each year. PM or aerosol, is difficult to characterize because of its wide range of particle sizes, constituents (various organic and inorganic compounds), concentration ...
EPFL2021
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The invention relates to a cross-linkable polymer comprising a base polymer comprising functional groups at least some of which have been reacted with a first organic molecule comprising a cross-linkable unit and with a second organic molecule capable of b ...
2020
Hybrid materials constructed from the assembly of inorganic building blocks and organic linkers have shown unique properties and applications. Superstructures of semiconductor magic-sized nanoclusters linked by diamines now join this class of materials. ...
NATURE RESEARCH2021
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We report an oxidative ring-opening strategy to transform cyclopropylamides and cyclobutylamides into fluorinated imines. The imines can be isolated in their more stable hemiaminal form, with the fluorine atom installed selectively at the gamma or delta po ...
WILEY-V C H VERLAG GMBH2020
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Atmospheric particulate matter (PM) is a complex mixture of many different substances and requires a suite of instruments for chemical characterization. Fourier transform infrared (FT-IR) spectroscopy is a technique that can provide quantification of multi ...
2019
Helium nanodroplets are liquid, finite size, nanoscale helium clusters that have been employed since the 1990s as a matrix for high-resolution spectroscopy of molecules. Spectroscopic studies of ionic species inside helium droplets were not however realise ...
The application of electrospray (ES) for quantitative transfer of analytes from solution to an internal reflection element for analysis by Attenuated Total Reflectance - Fourier Transform Infrared (ATR-FTIR) spectroscopy has been developed in this work. Th ...
Herein, we report a cysteine bioconjugation methodology for the introduction of hypervalent iodine compounds onto biomolecules. Ethynylbenziodoxolones (EBXs) engage thiols in small organic molecules and cysteine-containing peptides and proteins in a fast a ...