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Kinetic Network Modeling of the Catalytic Upgrading of Biomass's Acetate Fraction to Aromatics

Publications associées (35)

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Incremental Identification of Kinetic Models by Online Spectroscopy and Multivariate Calibration

Laurent Brandinu

Extent-based kinetic identification is a modeling technique that uses number of moles / concentrations measurements to compute extents and identify reaction kinetics (partial orders of reactions and reaction rate constant) by the integral method of paramet ...

2015

Effect of ammonia on the decomposition of ammonium formate over Au/TiO2 under oxidizing conditions relevant to SCR: Enhancement of formic acid decomposition rate and CO2 production

Oliver Kröcher

Ammonium formate (AmFo) and formic acid decomposition were carried out in the presence of excess O-2 and H2O over 0.5 wt%Au/TiO2 anatase monolithic catalysts using various contact times and temperatures between 160 degrees C and 300 degrees C, under spray ...

Elsevier Science Bv2014

Contributions to Spatial Statistics

Emeric Rolland Georges Thibaud

This thesis proposes some contributions to the spatial modelling of species distributions and extreme values. Predictive models are increasingly used to model the distribution of species and to estimate the potential effects of global change on biodiversit ...

EPFL2014

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The identification of kinetic models is an important step for the monitoring, control and optimization of industrial processes. This is particularly the case for highly competitive business sectors such as chemical and pharmaceutical industries, where the ...

2013

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The identification of kinetic models is an essential step for the monitoring, control and optimization of industrial processes. This is particularly true for the chemical and pharmaceutical industries, where the current trend of strong competition calls fo ...

2012

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Detailed thermodynamic and kinetic study of the aqueous Kolbe-Schmitt synthesis of beta-resorcylic acid has been carried out in a laboratory-scale batch reactor operated under ambient pressure. The dependence of the conversion on partial pressure of carbon ...

Elsevier2012

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The identification of reaction kinetics involves the determination of a model structure (reaction stoichiometry, rate laws for all reactions) and its corresponding parameters from experimental data. An incremental identification approach for determining th ...

2011

Nitrous Oxide Abatement over Fe-Zeolite

Bryan Bromley

The use of zeolites for catalytic reactions is a field in continuous development. Since it was demonstrated that metal-zeolites are efficient catalysts for NOx abatement, decomposition of nitrous oxide (N2O) over Fe-containing zeolites has attracted great ...

EPFL2010

Theoretical evidence of the observed kinetic order dependence on temperature during the N2O decomposition over Fe-ZSM-5

Lioubov Kiwi, Bryan Bromley

The characterization of Fe/ZSM5 zeolite materials, the nature of Fe-sites active in N2O direct decomposition, as well as the rate limiting step are still a matter of debate. The mechanism of N2O decomposition on the binuclear oxo-hydroxo bridged extraframe ...

Royal Society of Chemistry2010

Zinc Chloride Promoted Formal Oxidative Coupling of Aromatic Aldehydes and Isocyanides to alpha -Ketoamides

Jieping Zhu

Reaction of arom. aldehydes and isocyanides in the presence of N-methylhydroxyamine, acetic acid, and zinc chloride affords the aryl alpha -ketoamides, e.g. I, in moderate to good yields. [on SciFinder (R)] ...

2010