Microbial growth by a net heat up-take: a calorimetric and thermodynamic study on acetotrophic methanogenesis by Methanosarcina barkeri
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The enthalpies of formation of the intermetallic compounds in the Ge-Ni binary system have been determined by calorimetric measurement and first-principles calculations. Based on the results obtained and information available in the literature, the phase d ...
When adsorbing guest molecules, the porous metal-organic framework MIL-53(Cr) may vary its cell parameters drastically while retaining its crystallinity. A first approach to the thermodynamic analysis of this "framework breathing" consists of comparing the ...
Various aspects of the built environment have important effects on ecology. Providing suitable metrics for the built forms so as to quantify and model their internal relations and external ecological footprints, however, remains a challenge. Here we provid ...
Detailed thermodynamic and kinetic study of the aqueous Kolbe-Schmitt synthesis of beta-resorcylic acid has been carried out in a laboratory-scale batch reactor operated under ambient pressure. The dependence of the conversion on partial pressure of carbon ...
Thermodynamic irreversibility can be imposed on empirical material behaviour by using an appropriate algorithm which takes the path-dependence of the degradation process into account. This new algorithm, Algorithmically Imposed Mechanics (AIM), for algorit ...
Abstract—In this paper, the ‘Approximate Message Passing’ (AMP) algorithm, initially developed for compressed sensing of signals under i.i.d. Gaussian measurement matrices, has been extended to a multi-terminal setting (MAMP algorithm). It has been shown t ...
The coil to globule transition is a fundamental phenomenon in the physics of macro-molecules by reason of the multiplicity of arrangements of their conformation. Such conformational freedom is the main source of entropy in the molecule and is the main oppo ...
Chloramines, bromamines, and bromochloramines are halogen-containing oxidants that arise from the reaction of hypohalous acids with ammonia in water. Although relevant to both water disinfection chemistry and biochemistry, these molecules are difficult to ...
Phase equilibria in the Au-Cu-Ge ternary system, including the solid state phase relations at 450 degrees C as well as four vertical sections, were studied by means of scanning electron microscopy (SEM), electron probe microanalysis (EPMA), X-ray diffracti ...
Density functional calculations applying periodic boundary conditions have been performed to investigate adsorption and cracking of light alkanes (C 3-C 6) on zeolite H-ZSM-5. Intrinsic energy barriers were obtained from single-point calculations by applyi ...