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Concept
Geometrical frustration
Summary
In condensed matter physics, the term geometrical frustration (or in short: frustration) refers to a phenomenon where atoms tend to stick to non-trivial positions or where, on a regular crystal lattice, conflicting inter-atomic forces (each one favoring rather simple, but different structures) lead to quite complex structures. As a consequence of the frustration in the geometry or in the forces, a plenitude of distinct ground states may result at zero temperature, and usual thermal ordering may be suppressed at higher temperatures. Much studied examples are amorphous materials, glasses, or dilute magnets.
The term frustration, in the context of magnetic systems, has been introduced by Gerard Toulouse in 1977. Frustrated magnetic systems had been studied even before. Early work includes a study of the Ising model on a triangular lattice with nearest-neighbor spins coupled antiferromagnetically, by G. H. Wannier, published in 1950. Related features occur in magnets with competing interactions, where both ferromagnetic as well as antiferromagnetic couplings between pairs of spins or magnetic moments are present, with the type of interaction depending on the separation distance of the spins. In that case commensurability, such as helical spin arrangements may result, as had been discussed originally, especially, by A. Yoshimori, T. A. Kaplan, R. J. Elliott, and others, starting in 1959, to describe experimental findings on rare-earth metals. A renewed interest in such spin systems with frustrated or competing interactions arose about two decades later, beginning in the 1970s, in the context of spin glasses and spatially modulated magnetic superstructures. In spin glasses, frustration is augmented by stochastic disorder in the interactions, as may occur experimentally in non-stoichiometric magnetic alloys. Carefully analyzed spin models with frustration include the Sherrington–Kirkpatrick model, describing spin glasses, and the ANNNI model, describing commensurability magnetic superstructures.
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Related concepts (10)
Geometrical frustration
In condensed matter physics, the term geometrical frustration (or in short: frustration) refers to a phenomenon where atoms tend to stick to non-trivial positions or where, on a regular crystal lattice, conflicting inter-atomic forces (each one favoring rather simple, but different structures) lead to quite complex structures. As a consequence of the frustration in the geometry or in the forces, a plenitude of distinct ground states may result at zero temperature, and usual thermal ordering may be suppressed at higher temperatures.
Residual entropy
Residual entropy is the difference in entropy between a non-equilibrium state and crystal state of a substance close to absolute zero. This term is used in condensed matter physics to describe the entropy at zero kelvin of a glass or plastic crystal referred to the crystal state, whose entropy is zero according to the third law of thermodynamics. It occurs if a material can exist in many different states when cooled. The most common non-equilibrium state is vitreous state, glass.
Order and disorder
In physics, the terms order and disorder designate the presence or absence of some symmetry or correlation in a many-particle system. In condensed matter physics, systems typically are ordered at low temperatures; upon heating, they undergo one or several phase transitions into less ordered states. Examples for such an order-disorder transition are: the melting of ice: solid-liquid transition, loss of crystalline order; the demagnetization of iron by heating above the Curie temperature: ferromagnetic-paramagnetic transition, loss of magnetic order.
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