A topological insulator is a material whose interior behaves as an electrical insulator while its surface behaves as an electrical conductor, meaning that electrons can only move along the surface of the material.
A topological insulator is an insulator for the same reason a "trivial" (ordinary) insulator is: there exists an energy gap between the valence and conduction bands of the material. But in a topological insulator, these bands are, in an informal sense, "twisted", relative to a trivial insulator. The topological insulator cannot be continuously transformed into a trivial one without untwisting the bands, which closes the band gap and creates a conducting state. Thus, due to the continuity of the underlying field, the border of a topological insulator with a trivial insulator (including vacuum, which is topologically trivial) is forced to support a conducting state.
Since this results from a global property of the topological insulator's band structure, local (symmetry-preserving) perturbations cannot damage this surface state. This is unique to topological insulators: while ordinary insulators can also support conductive surface states, only the surface states of topological insulators have this robustness property.
This leads to a more formal definition of a topological insulator: an insulator which cannot be adiabatically transformed into an ordinary insulator without passing through an intermediate conducting state. In other words, topological insulators and trivial insulators are separate regions in the phase diagram, connected only by conducting phases. In this way, topological insulators provide an example of a state of matter not described by the Landau symmetry-breaking theory that defines ordinary states of matter.
The properties of topological insulators and their surface states are highly dependent on both the dimension of the material and its underlying symmetries, and can be classified using the so-called periodic table of topological insulators. Some combinations of dimension and symmetries forbid topological insulators completely.
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