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Concept
Condensation
Summary
Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition.
Condensation is initiated by the formation of atomic/molecular clusters of that species within its gaseous volume—like rain drop or snow flake formation within clouds—or at the contact between such gaseous phase and a liquid or solid surface. In clouds, this can be catalyzed by water-nucleating proteins, produced by atmospheric microbes, which are capable of binding gaseous or liquid water molecules.
A few distinct reversibility scenarios emerge here with respect to the nature of the surface.
absorption into the surface of a liquid (either of the same substance or one of its solvents)—is reversible as evaporation.
adsorption (as dew droplets) onto solid surface at pressures and temperatures higher than the species' triple point—also reversible as evaporation.
adsorption onto solid surface (as supplemental layers of solid) at pressures and temperatures lower than the species' triple point—is reversible as sublimation.
Condensation commonly occurs when a vapor is cooled and/or compressed to its saturation limit when the molecular density in the gas phase reaches its maximal threshold. Vapor cooling and compressing equipment that collects condensed liquids is called a "condenser".
Psychrometry measures the rates of condensation through evaporation into the air moisture at various atmospheric pressures and temperatures. Water is the product of its vapor condensation—condensation is the process of such phase conversion.
Condensation is a crucial component of distillation, an important laboratory and industrial chemistry application.
Official source
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