Expectation value (quantum mechanics)In quantum mechanics, the expectation value is the probabilistic expected value of the result (measurement) of an experiment. It can be thought of as an average of all the possible outcomes of a measurement as weighted by their likelihood, and as such it is not the most probable value of a measurement; indeed the expectation value may have zero probability of occurring (e.g. measurements which can only yield integer values may have a non-integer mean). It is a fundamental concept in all areas of quantum physics.
Canonical commutation relationIn quantum mechanics, the canonical commutation relation is the fundamental relation between canonical conjugate quantities (quantities which are related by definition such that one is the Fourier transform of another). For example, between the position operator x and momentum operator px in the x direction of a point particle in one dimension, where [x , px] = x px − px x is the commutator of x and px , i is the imaginary unit, and ħ is the reduced Planck's constant h/2π, and is the unit operator.
