A refrigerant is a working fluid used in the refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are heavily regulated due to their toxicity, flammability and the contribution of CFC and HCFC refrigerants to ozone depletion and that of HFC refrigerants to climate change.
Refrigerants are used in a direct expansion (DX) system to transfer energy from one environment to another, typically from inside a building to outside (or vice versa) commonly known as an "air conditioner" or "heat pump". Refrigerants can carry per kg 10 times more energy than water and 50 times more than air.
Refrigerants are controlled substances due to high pressures (100-145 psi), extreme temperatures (-50°C to over 100°C), flammability (A1 class non-flammable, A2/A2L class flammable and A3 class extremely flammable/explosive) and toxicity (B1-low, B2-medium & B3-high), as classified by ISO 817 & ASHRAE 34.
Refrigerants must only be handled by qualified/certified engineers to the relevant classes of refrigerant eg in the UK C&G 2079 if A1 class PLUS C&G 6187-2 if A2/A2L & A3 class refrigerants.
The first air conditioners and refrigerators employed toxic or flammable gases, such as ammonia, sulfur dioxide, methyl chloride, or propane, that could result in fatal accidents when they leaked.
In 1928 Thomas Midgley Jr. created the first non-flammable, non-toxic chlorofluorocarbon gas, Freon (R-12). The name is a trademark name owned by DuPont (now Chemours) for any chlorofluorocarbon (CFC), hydrochlorofluorocarbon (HCFC), or hydrofluorocarbon (HFC) refrigerant. Following the discovery of better synthesis methods, CFCs such as R-11, R-12, R-123 and R-502 dominated the market.
Montreal Protocol
In the early 1980s, scientists discovered that CFCs were causing major damage to the ozone layer that protects the earth from ultraviolet radiation, and to the ozone holes over polar regions.
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The carbon–fluorine bond is a polar covalent bond between carbon and fluorine that is a component of all organofluorine compounds. It is one of the strongest single bonds in chemistry (after the B–F single bond, Si–F single bond, and H–F single bond), and relatively short, due to its partial ionic character. The bond also strengthens and shortens as more fluorines are added to the same carbon on a chemical compound. As such, fluoroalkanes like tetrafluoromethane (carbon tetrafluoride) are some of the most unreactive organic compounds.
There are several known allotropes of oxygen. The most familiar is molecular oxygen (), present at significant levels in Earth's atmosphere and also known as dioxygen or triplet oxygen. Another is the highly reactive ozone (). Others are: Atomic oxygen (), a free radical. Singlet oxygen (O2*), one of two metastable states of molecular oxygen. Tetraoxygen (), another metastable form. Solid oxygen, existing in six variously colored phases, of which one is octaoxygen (,red oxygen) and another one metallic (ζ-oxygen).
Trace gases are gases that are present in small amounts within an environment such as a planet's atmosphere. Trace gases in Earth's atmosphere are gases other than nitrogen (78.1%), oxygen (20.9%), and argon (0.934%) which, in combination, make up 99.934% of its atmosphere (not including water vapor). The abundance of a trace gas can range from a few parts per trillion (ppt) by volume to several hundred parts per million by volume (ppmv). When a trace gas is added into the atmosphere, that process is called a source.
The course equips students with a comprehensive scientific understanding of climate change covering a wide range of topics from physical principles, historical climate change, greenhouse gas emissions
The course provides an introduction to the physical and chemical processes that govern the atmospheric dynamics at small and large scales. The basis is laid for an in depth understanding of our atmosp
A chemical substance is a form of matter having constant chemical composition and characteristic properties. Chemical substances can be simple substances (substances consisting of a single chemical element), chemical compounds, or alloys. Chemical substances that cannot be separated into their simpler constituent elements by physical means are said to be 'pure'; this notion intended to set them apart from mixtures.
In chemistry, many authors consider an organic compound to be any chemical compound that contains carbon-hydrogen or carbon-carbon bonds, however, some authors consider an organic compound to be any chemical compound that contains carbon. The definition of "organic" versus "inorganic" varies from author to author, and is a topic of debate. For example, methane () is considered organic, but whether some other carbon-containing compounds are organic or inorganic varies from author to author, for example halides of carbon without carbon-hydrogen and carbon-carbon bonds (e.
Climate change mitigation is action to limit climate change by reducing emissions of greenhouse gases or removing those gases from the atmosphere. The recent rise in global average temperature is mostly due to emissions from burning fossil fuels such as coal, oil, and natural gas. Mitigation can reduce emissions by transitioning to sustainable energy sources, conserving energy, and increasing efficiency. It is possible to remove carbon dioxide () from the atmosphere by enlarging forests, restoring wetlands and using other natural and technical processes.
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Nanocluster aerosols (NCA, particles
Pergamon-Elsevier Science Ltd2024
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Emulsions are omnipresent in our everyday life; for example, in food, certain drug and cosmetic formulations, agriculture, and as paints. Moreover, they are frequently used to perform high-throughput screening assays with minimum sample volumes. Key to the ...