Publications related to Vaska's complex

The acid-mediated isomerization of iridium(iii) complexes with cyclometalated NHC ligands: kinetic vs. thermodynamic control

Kay Severin, Farzaneh Fadaei Tirani, Anastasia Gitlina

The isomerization of iridium(III) complexes with metalated N-heterocyclic carbene (NHC) ligands was studied. The fac isomers of complexes with 1-phenyl-3-methylbenzimidazolin-2-ylidene or 1-phenyl-3-benzylbenzimidazolin-2-ylidene ligands are transformed cl ...

2023

Charge ordering in Ir dimers in the ground state of Ba5AlIr2O11

Oleg Yazyev, Thorsten Schmitt, Vladimir N. Strocov, Vamshi Mohan Katukuri, Xingye Lu

It has been well established experimentally that the interplay of electronic correlations and spin-orbit interactions in Ir4+ and Ir5+ oxides results in insulating J(eff) = 1/2 and J(eff) = 0 ground states, respectively. However, in compounds where the str ...

AMER PHYSICAL SOC2022

Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities

Rosario Scopelliti

To investigate the effect of different halogen substituents and leaving groups and the flexibility of ligands on the anticancer activity of copper complexes, sixteen copper(ii) complexes with eight different tridentate Schiff-base ligands containing pyridi ...

ROYAL SOC CHEMISTRY2021

Phosphorescent Neutral Iridium (III) Complexes for Organic Light-Emitting Diodes

Mohammad Khaja Nazeeruddin, Aron Joel Huckaba

The development of transition metal complexes for application in light-emitting devices is currently attracting significant research interest. Among phosphorescent emitters, those involving iridium (III) complexes have proven to be exceedingly useful due t ...

Springer Verlag2017

Cyanide Single-Molecule Magnets Exhibiting Solvent Dependent Reversible "On" and "Off" Exchange Bias Behavior

Jan Gui-Hyon Dreiser

The syntheses, structures, and magnetic properties of four new complex salts, (PPN){Mn-III(salphen)(MeOH)[M-III(CN)(6)]} 7MeOH (Mn2M 7MeOH) (M = Fe, Ru, Os and Co; PPN+ = bis(triphenylphosphoranylidene)ammonium cation; H2salphen = N,N'-bis(salicyliden ...

American Chemical Society2015

Vibrationally Promoted Dissociation of Water on Ni(111)

Rainer Beck, Phil Morten Hundt

Water dissociation on transition-metal catalysts is an important step in steam reforming and the water-gas shift reaction. To probe the effect of translational and vibrational activation on this important heterogeneous reaction, we performed state-resolved ...

Amer Assoc Advancement Science2014

Characterization of high-spin metal-carbonyls in metal-organic frameworks with exposed cation sites

Wendy Lee Queen

The metal-org. frameworks M2(dobdc) (dobdc4- = 2,5-dioxido-1,4-benzenedicarboxylate, MOF-74, CPO-27) (M = Mg, Mn, Fe, Co, Ni, Zn) have shown considerable promise for a no. of gas storage and sepn. applications. These have included CO2/N2, CO2/H2, O2/N2, an ...

American Chemical Society2014

Molecular Orbital Gates for Plasmon Excitation

Klaus Kern, Uta Schlickum, Christian Alexander Stephan Dette, Theresa Lutz, Christoph Grosse, Alexander Kabakchiev

Future combinations of plasmonics with nanometer-size electronic circuits require strategies to control the electrical excitation of plasmons at the length scale of individual molecules. A unique tool to study the electrical plasmon excitation with ultimat ...

Amer Chemical Soc2013

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Vaska's complex

The acid-mediated isomerization of iridium(iii) complexes with cyclometalated NHC ligands: kinetic vs. thermodynamic control

A concept for the extraction of the most refractory elements at CERN-ISOLDE as carbonyl complex ions

Charge ordering in Ir dimers in the ground state of Ba5AlIr2O11

Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities

Phosphorescent Neutral Iridium (III) Complexes for Organic Light-Emitting Diodes

Cyanide Single-Molecule Magnets Exhibiting Solvent Dependent Reversible "On" and "Off" Exchange Bias Behavior

Renormalization of myoglobin-ligand binding energetics by quantum many-body effects

Vibrationally Promoted Dissociation of Water on Ni(111)

Characterization of high-spin metal-carbonyls in metal-organic frameworks with exposed cation sites

Molecular Orbital Gates for Plasmon Excitation

Graph Chatbot

Chat with Graph Search

Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities

Molecular Orbital Gates for Plasmon Excitation

Phosphorescent Neutral Iridium (III) Complexes for Organic Light-Emitting Diodes

Cyanide Single-Molecule Magnets Exhibiting Solvent Dependent Reversible "On" and "Off" Exchange Bias Behavior

Renormalization of myoglobin-ligand binding energetics by quantum many-body effects

A concept for the extraction of the most refractory elements at CERN-ISOLDE as carbonyl complex ions

Charge ordering in Ir dimers in the ground state of Ba5AlIr2O11

The acid-mediated isomerization of iridium(iii) complexes with cyclometalated NHC ligands: kinetic vs. thermodynamic control

Vibrationally Promoted Dissociation of Water on Ni(111)

Characterization of high-spin metal-carbonyls in metal-organic frameworks with exposed cation sites