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Concept
Potassium hydroxide
Summary
Potassium hydroxide is an inorganic compound with the formula KOH, and is commonly called caustic potash.
Along with sodium hydroxide (NaOH), KOH is a prototypical strong base. It has many industrial and niche applications, most of which exploit its caustic nature and its reactivity toward acids. An estimated 700,000 to 800,000 tonnes were produced in 2005. KOH is noteworthy as the precursor to most soft and liquid soaps, as well as numerous potassium-containing chemicals. It is a white solid that is dangerously corrosive.
KOH exhibits high thermal stability. Because of this high stability and relatively low melting point, it is often melt-cast as pellets or rods, forms that have low surface area and convenient handling properties. These pellets become tacky in air because KOH is hygroscopic. Most commercial samples are ca. 90% pure, the remainder being water and carbonates. Its dissolution in water is strongly exothermic. Concentrated aqueous solutions are sometimes called potassium lyes. Even at high temperatures, solid KOH does not dehydrate readily.
At higher temperatures, solid KOH crystallizes in the NaCl crystal structure. The group is either rapidly or randomly disordered so that it is effectively a spherical anion of radius 1.53 Å (between and in size). At room temperature, the groups are ordered and the environment about the centers is distorted, with distances ranging from 2.69 to 3.15 Å, depending on the orientation of the OH group. KOH forms a series of crystalline hydrates, namely the monohydrate , the dihydrate and the tetrahydrate .
About 121 g of KOH dissolve in 100 mL water at room temperature, which contrasts with 100 g/100 mL for NaOH. Thus on a molar basis, NaOH is slightly more soluble than KOH. Lower molecular-weight alcohols such as methanol, ethanol, and propanols are also excellent solvents. They participate in an acid-base equilibrium. In the case of methanol the potassium methoxide (methylate) forms:
Because of its high affinity for water, KOH serves as a desiccant in the laboratory.
Official source
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