Publications related to Pentamethylcyclopentadiene

Mapping Catalyst‐Solvent Interplay in Competing Carboamination/Cyclopropanation Reactions

Nicolai Cramer, Matthew Wodrich, Miyeon Chang, Simone Gallarati

Group 9 metals, in particular Rh III complexes with cyclopentadienyl ligands, are competent C–H activation catalysts. Recently, a Cp*Rh III catalyzed reaction of alkenes with N -enoxyphthalimides showed divergent outcome based on the solvent, with carboami ...

2022

Mediated water electrolysis in biphasic systems

Hubert Girault, Pekka Eero Peljo, Heron Vrubel, Micheal Diarmaid Scanlon, Lucie Josette Renée Rivier

The concept of efficient electrolysis by linking photoelectrochemical biphasic H2 evolution and water oxidation processes in the cathodic and anodic compartments of an H-cell, respectively, is introduced. Overpotentials at the cathode and anode are minimis ...

Royal Society of Chemistry2017

Tribocorrosion and electrochemical behaviour of nanocrystalline diamond coated Ti based alloys for orthopaedic application

Stefano Mischler, Shoufan Cao

Metallic implants such as hip and knee often fail due to the combined action of wear and corrosion. Nanocrystalline diamond (NCD) coatings on metallic implants can be a potential candidate to overcome this issue. In this work, we investigated the tribocorr ...

Elsevier2017

Cytotoxic Half-Sandwich Rh(III) and Ir(III) beta-Diketonates

Paul Joseph Dyson, Rosario Scopelliti, Tina Riedel, Agnese Petrini

A series of half-sandwich pentamethylcyclopentadienyl rhodium(III) and iridium(III) complexes [CpM(DBM/ HDB/AVB)Cl] and [CpM(DBM/HDB/AVB)(PTA)]-[SO3CF3], where Cp* = pentamethylcyclopentadienyl, the proligands DBMH = dibenzoylmethane, HDBH = o-hydroxydi- ...

American Chemical Society2017

A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes

Nicolai Cramer, Matthew Wodrich, Benoît Daniel Bertrand Audic, Gints Smits

The electronic and steric properties of tailored cyclopentadienyl (Cp) ligands are powerful handles to modulate the catalytic properties of their metal complexes. This requires the individual preparation, purification and storage of each ligand/metal combi ...

2017

Organometallic rhodium(III) and iridium(III) cyclopentadienyl complexes with curcumin and bisdemethoxycurcumin co-ligands

Paul Joseph Dyson, Rosario Scopelliti, Tina Riedel, Agnese Petrini

A series of half-sandwich cyclopentadienyl rhodium(III) and iridium(III) complexes of the type [CpM(curc/bdcurc) Cl] and [CpM(curc/bdcurc)(PTA)][SO3CF3], in which Cp* = pentamethylcyclopentadienyl, curcH = curcumin and bdcurcH = bisdemethoxycurcumin as O ...

2015

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C-H Functionalizations

Nicolai Cramer, Baihua Ye

Transition-metal catalyzed C-H functionalizations became a complementary and efficient bond-forming strategy over the past decade. In this respect, Cp*Rh(III) complexes have emerged as powerful catalysts for a broad spectrum of reactions giving access to s ...

American Chemical Society2015

Chiral Cp-Rhodium(III)-Catalyzed Asymmetric Hydroarylations of 1,1-Disubstituted Alkenes

Nicolai Cramer, Baihua Ye, Pavel Alexandrovich Donets

Metal-catalyzed functionalizations at the ortho position of a directing group have become an efficient bond-forming strategy. A wide range of transformations that employ Cp*Rh-III catalysts have been described, but despite their synthetic potential, enanti ...

Wiley-V C H Verlag Gmbh2014

Modulating the Steric, Electronic, and Catalytic Properties of Cp* Ruthenium Half-Sandwich Complexes with β-Diketiminato Ligands

Paul Joseph Dyson, Rosario Scopelliti, Kay Severin, Andrew Douglas Phillips, Katrin Anne Thommes, Dominique Schreiber

Five different types of β-diketiminate ligands, bearing electron-donating to strongly electron-withdrawing substituents, were synthesized and used in the synthesis of Cp* ruthenium complexes (Cp* = η5-C5Me5). One series consists of complexes with a covalen ...

American Chemical Society2011

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Pentamethylcyclopentadiene

Mapping Catalyst‐Solvent Interplay in Competing Carboamination/Cyclopropanation Reactions

Mediated water electrolysis in biphasic systems

Tribocorrosion and electrochemical behaviour of nanocrystalline diamond coated Ti based alloys for orthopaedic application

Cytotoxic Half-Sandwich Rh(III) and Ir(III) beta-Diketonates

A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes

Organometallic rhodium(III) and iridium(III) cyclopentadienyl complexes with curcumin and bisdemethoxycurcumin co-ligands

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C-H Functionalizations

Iron Complexes for Hydrogen Activation and Catalytic Hydrogenation

Chiral Cp-Rhodium(III)-Catalyzed Asymmetric Hydroarylations of 1,1-Disubstituted Alkenes

Modulating the Steric, Electronic, and Catalytic Properties of Cp* Ruthenium Half-Sandwich Complexes with β-Diketiminato Ligands

Graph Chatbot

Chat with Graph Search

Mapping Catalyst‐Solvent Interplay in Competing Carboamination/Cyclopropanation Reactions

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C-H Functionalizations

Tribocorrosion and electrochemical behaviour of nanocrystalline diamond coated Ti based alloys for orthopaedic application

Organometallic rhodium(III) and iridium(III) cyclopentadienyl complexes with curcumin and bisdemethoxycurcumin co-ligands

Chiral Cp-Rhodium(III)-Catalyzed Asymmetric Hydroarylations of 1,1-Disubstituted Alkenes

Cytotoxic Half-Sandwich Rh(III) and Ir(III) beta-Diketonates

Iron Complexes for Hydrogen Activation and Catalytic Hydrogenation

Mediated water electrolysis in biphasic systems

A β-Carbon elimination strategy for convenient in situ access to cyclopentadienyl metal complexes

Modulating the Steric, Electronic, and Catalytic Properties of Cp* Ruthenium Half-Sandwich Complexes with β-Diketiminato Ligands