Evidence for a diffusion-based mechanism of liquid metal intergranular penetration : case study of a Ni-Bi model system
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This work is motivated by an industrial interest in gaining a better understanding of the phase transformations that govern the mechanical properties of 18-carat gold alloys commonly used in jewelry applications and luxury watchmaking. These alloys fall in ...
The dynamics and bonding of the complex hydrides LiBH4 and LiAlH4 have been investigated by vibrational spectroscopy. The combination of infrared, Raman, and inelastic neutron scattering (INS) spectroscopies on hydrided and deuterided samples reveals a com ...
Until about the year 2030, current-day nuclear power plants (NPPs) will be replaced by so-called Gen-III or Gen-III+ units, which are mainly based on light water reactor technology. The principal new features are increased safety and improved economical ef ...
This paper presents a methodology for the optimal design and operation of man-portable power generation devices based on fuel cells. To illustrate the methodology, we focus on a simple process that consists of a fuel processing reactor, a solid-oxide fuel ...
The evolution of the polariton condensation threshold (P-thr) under incoherent optical pumping is investigated both theoretically and experimentally over a wide range of temperatures (4-340 K) and exciton-cavity photon detunings (-120-0 meV) in a multiple ...
Reliability of SOFC stacks is a complex and key issue. This paper presents a simulation study including some degradation processes, namely, interconnect degradation and the anode reoxidation potential. Quantification for these phenomena has been included i ...
Grain boundaries (GBs) play an important role for the mechanical properties of metals. In addition to dislocation motion inside the grains, some metal alloys deform along the GBs at high temperatures. GBs can also be the cause of a brittle behaviour of som ...
Intergranular penetration of liquid bismuth has been analysed in two pure metals, Cu at 500°C and Ni at 700°C, used either as polycrystals or as oriented bicrystals. At the liquid/solid interface, large grooves have developed in Cu-Bi, while micrometer-thi ...
Heavily deformed 18-carat yellow gold samples show a recrystallization peak at 700 K during the first heating. The mechanical loss spectrum of polycrystals shows a relaxation peak at about 780 K, which is absent in single crystals made from the same alloy. ...
The possibility to increase the performance (productivity or selectivity) of a chemical reactor by using periodic variations of reaction parameters (e.g. reactant concentration or temperature) has been theoretically envisaged since the beginning of the 70t ...