Upper critical solution temperatureThe upper critical solution temperature (UCST) or upper consolute temperature is the critical temperature above which the components of a mixture are miscible in all proportions. The word upper indicates that the UCST is an upper bound to a temperature range of partial miscibility, or miscibility for certain compositions only. For example, hexane-nitrobenzene mixtures have a UCST of , so that these two substances are miscible in all proportions above but not at lower temperatures.
Lower critical solution temperatureThe lower critical solution temperature (LCST) or lower consolute temperature is the critical temperature below which the components of a mixture are miscible in all proportions. The word lower indicates that the LCST is a lower bound to a temperature interval of partial miscibility, or miscibility for certain compositions only. The phase behavior of polymer solutions is an important property involved in the development and design of most polymer-related processes.
Standard temperature and pressureStandard temperature and pressure (STP) are various standard sets of conditions for experimental measurements to be established to allow comparisons to be made between different sets of data. The most used standards are those of the International Union of Pure and Applied Chemistry (IUPAC) and the National Institute of Standards and Technology (NIST), although these are not universally accepted standards. Other organizations have established a variety of alternative definitions for their standard reference conditions.
Metallic bondingMetallic bonding is a type of chemical bonding that arises from the electrostatic attractive force between conduction electrons (in the form of an electron cloud of delocalized electrons) and positively charged metal ions. It may be described as the sharing of free electrons among a structure of positively charged ions (cations). Metallic bonding accounts for many physical properties of metals, such as strength, ductility, thermal and electrical resistivity and conductivity, opacity, and luster.
Greenhouse gas emissions from wetlandsGreenhouse gas emissions from wetlands of concern consist primarily of methane and nitrous oxide emissions. Wetlands are the largest natural source of atmospheric methane in the world, and therefore remain a major area of concern with respect to climate change. They contribute approximately 167 Tg of methane to the atmosphere per year. Wetlands account for approximately 20 percent of atmospheric methane through emissions from soils and plants.
Activation energyIn chemistry and physics, activation energy is the minimum amount of energy that must be provided for compounds to result in a chemical reaction. The activation energy (Ea) of a reaction is measured in joules per mole (J/mol), kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol). Activation energy can be thought of as the magnitude of the potential barrier (sometimes called the energy barrier) separating minima of the potential energy surface pertaining to the initial and final thermodynamic state.
Sidereal timeSidereal time ("sidereal" pronounced saɪˈdɪəriəl,_sə- ) is a system of timekeeping used especially by astronomers. Using sidereal time and the celestial coordinate system, it is easy to locate the positions of celestial objects in the night sky. Sidereal time is a "time scale that is based on Earth's rate of rotation measured relative to the fixed stars". Viewed from the same location, a star seen at one position in the sky will be seen at the same position on another night at the same time of day (or night), if the day is defined as a sidereal day (also known as the sidereal rotation period).
Henry's lawIn physical chemistry, Henry's law is a gas law that states that the amount of dissolved gas in a liquid is directly proportional to its partial pressure above the liquid. The proportionality factor is called Henry's law constant. It was formulated by the English chemist William Henry, who studied the topic in the early 19th century. An example where Henry's law is at play is in the depth-dependent dissolution of oxygen and nitrogen in the blood of underwater divers that changes during decompression, leading to decompression sickness.
Salt (chemistry)In chemistry, a salt is a chemical compound consisting of an ionic assembly of positively charged cations and negatively charged anions, which results in a compound with no net electric charge. A common example is table salt, with positively charged sodium ions and negatively charged chloride ions. The component ions in a salt compound can be either inorganic, such as chloride (Cl−), or organic, such as acetate (CH3COO−). Each ion can be either monatomic, such as fluoride (F−), or polyatomic, such as sulfate (SO42−).
Solar timeSolar time is a calculation of the passage of time based on the position of the Sun in the sky. The fundamental unit of solar time is the day, based on the synodic rotation period. Traditionally, there are three types of time reckoning based on astronomical observations: apparent solar time and mean solar time (discussed in this article), and sidereal time, which is based on the apparent motions of stars other than the Sun. A tall pole vertically fixed in the ground casts a shadow on any sunny day.
