Hiyama couplingThe Hiyama coupling is a palladium-catalyzed cross-coupling reaction of organosilanes with organic halides used in organic chemistry to form carbon–carbon bonds (C-C bonds). This reaction was discovered in 1988 by Tamejiro Hiyama and Yasuo Hatanaka as a method to form carbon-carbon bonds synthetically with chemo- and regioselectivity. The Hiyama coupling has been applied to the synthesis of various natural products.
Square matrixIn mathematics, a square matrix is a matrix with the same number of rows and columns. An n-by-n matrix is known as a square matrix of order . Any two square matrices of the same order can be added and multiplied. Square matrices are often used to represent simple linear transformations, such as shearing or rotation. For example, if is a square matrix representing a rotation (rotation matrix) and is a column vector describing the position of a point in space, the product yields another column vector describing the position of that point after that rotation.
Definite matrixIn mathematics, a symmetric matrix with real entries is positive-definite if the real number is positive for every nonzero real column vector where is the transpose of . More generally, a Hermitian matrix (that is, a complex matrix equal to its conjugate transpose) is positive-definite if the real number is positive for every nonzero complex column vector where denotes the conjugate transpose of Positive semi-definite matrices are defined similarly, except that the scalars and are required to be positive or zero (that is, nonnegative).
Kumada couplingIn organic chemistry, the Kumada coupling is a type of cross coupling reaction, useful for generating carbon–carbon bonds by the reaction of a Grignard reagent and an organic halide. The procedure uses transition metal catalysts, typically nickel or palladium, to couple a combination of two alkyl, aryl or vinyl groups. The groups of Robert Corriu and Makoto Kumada reported the reaction independently in 1972. The reaction is notable for being among the first reported catalytic cross-coupling methods.
Direct product of groupsIn mathematics, specifically in group theory, the direct product is an operation that takes two groups G and H and constructs a new group, usually denoted G × H. This operation is the group-theoretic analogue of the Cartesian product of sets and is one of several important notions of direct product in mathematics. In the context of abelian groups, the direct product is sometimes referred to as the direct sum, and is denoted .
Matrix additionIn mathematics, matrix addition is the operation of adding two matrices by adding the corresponding entries together. For a vector, , adding two matrices would have the geometric effect of applying each matrix transformation separately onto , then adding the transformed vectors. However, there are other operations that could also be considered addition for matrices, such as the direct sum and the Kronecker sum. Two matrices must have an equal number of rows and columns to be added.
Amplitude amplificationAmplitude amplification is a technique in quantum computing which generalizes the idea behind Grover's search algorithm, and gives rise to a family of quantum algorithms. It was discovered by Gilles Brassard and Peter Høyer in 1997, and independently rediscovered by Lov Grover in 1998. In a quantum computer, amplitude amplification can be used to obtain a quadratic speedup over several classical algorithms. The derivation presented here roughly follows the one given by Brassard et al. in 2000.
Quantum Fourier transformIn quantum computing, the quantum Fourier transform (QFT) is a linear transformation on quantum bits, and is the quantum analogue of the discrete Fourier transform. The quantum Fourier transform is a part of many quantum algorithms, notably Shor's algorithm for factoring and computing the discrete logarithm, the quantum phase estimation algorithm for estimating the eigenvalues of a unitary operator, and algorithms for the hidden subgroup problem. The quantum Fourier transform was discovered by Don Coppersmith.
Thermal conductivityThe thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by , , or . Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal conductivity. For instance, metals typically have high thermal conductivity and are very efficient at conducting heat, while the opposite is true for insulating materials like mineral wool or Styrofoam.
Linear differential equationIn mathematics, a linear differential equation is a differential equation that is defined by a linear polynomial in the unknown function and its derivatives, that is an equation of the form where a0(x), ..., an(x) and b(x) are arbitrary differentiable functions that do not need to be linear, and y′, ..., y(n) are the successive derivatives of an unknown function y of the variable x. Such an equation is an ordinary differential equation (ODE).
