A surface locking instability for atomic intercalation into a solid electrode
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Plastic flow is an important mechanism for relaxing stresses that develop due to swelling/shrinkage during charging/discharging of battery materials. Amorphous high-storage capacity Li-Si has lower flow stresses than crystalline materials but there is evid ...
The Li-ion batteries within the consumer electronics used in our everyday life suffer from well-known deficiencies due to the prevalent use of organic liquid electrolytes: the narrow electrochemical stability windows of the organic solvents used in these e ...
Sodium-ion technology is a reliable alternative to lithium-ion for large-scale energy storage because of the abundance of sodium sources and related low cost. In this work, we report about a simple fabrication of self-standing electrodes based on electrosp ...
Lithium-ion batteries provide the power for portable electronics and found many other interesting applications. It is desirable to design batteries with high energy density and long cycle life. Silicon is among the highest Li-storing anode materials in bat ...
A family of 2D transition metal carbides and nitrides known as MXenes has received increasing attention since the discovery of Ti3C2 in 2011. To date, about 30 different MXenes with well-defined structures and properties have been synthesized, and many mor ...
The structural and electrochemical properties of a quaternary layered compound with elemental composition Mn2Sb3O6Cl have been investigated upon reaction with lithium in Li half cells. Operando XRD was used to investigate the potential impact of this parti ...
Establishing a link between atomistic processes and battery cell behavior is a major challenge for lithium ion batteries. Focusing on liquid electrolytes, we describe parameter-free molecular dynamics predictions of their mass and charge transport properti ...
Chem. degrdn. at electrode/electrolyte interfaces in high-energy storage devices, such as Li-ion batteries, imposes durability challenges that affect their life and cost. In oxide electrodes, degrdn. is linked to the presence of redox active transition met ...
Within the context of the electrical circuit modeling of batteries, this paper proposes an improvement of the most common electric equivalent circuit used for Lithium cells. The main improvement is based on the modeling of the so-called charge redistributi ...
We have studied low-temperature magnetic properties as well as high-temperature lithium ion diffusion in the battery cathode materials LixNi1/3Co1/3Mn1/1O2 by the use of muon spin rotation/relaxation. Our data reveal that the samples enter into a 2D spin-g ...