Surface-Enhanced Hyper-Raman Scattering: A New Road to the Observation of Low Energy Molecular Vibrations
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We describe the use of stimulated Raman pumping in a molecular beam to perform quantum state resolved gas-surface reactivity measurements for molecules prepared in totally symmetric vibrational states. Vibrational states of homonuclear diatomics as well as ...
This work includes the fabrication of plasmonic nanostructures as well as the investigation of their optical properties in the near-field and in the farfield. As expressed in the title of this thesis the focus lies in the subwavelength confinement and enha ...
Disordered oxides, such as vitreous silica (v-SiO2) and vitreous germania, (v-GeO2) and chalcogenide glasses, such as vitreous germanium diselenide (v-GeSe2) are currently key materials in many technological fields, ranging from Si-based microelectronic to ...
We have investigated the polarization properties of photoluminescence and Raman scattering in strongly coupled organic microcavities containing cyanine dye J aggregates. The birefringence of radially aligned J aggregates results in a large energy splitting ...
We have fabricated gold nanospheres composite multilayer films using the layer-by-layer (LbL) self-assembly technique, and have investigated the aggregate states of the gold nanosphere. The gold nanospheres composite multilayer films were fabricated by con ...
In 2-color optical Kerr effect measurements of water, addnl. signals can occur in the pulse overlap region if the energy difference between pump and probe pulses approaches the Raman resonance of the OH-stretch vibration. These features can be understood b ...
Mixts. of methane, H, and Ar (CH4:H2:Ar) were studied as UV Raman shifters for ozone differential absorption lidar application. They have higher photochem. stability than pure CH4 and the capability to produce, with high enough efficiency, either 1st CH4 S ...
The different parts of the electromagnetic spectrum result in diverse effects upon interaction with matter: according to the wavelength, the radiation has energy appropriate for the excitation of a specific physical process. X-rays can be used as a tool to ...
We have investigated the thermal stability of GaN using Raman scattering. Noninvasive optical monitoring of structural damage to GaN by high-temperature anneals in nitrogen ambient has been demonstrated. Characteristic features in the Raman spectrum identi ...
A summary of results on the resonance Raman study of I2 in CCl4 and liq. Xe is presented. No discrete fluorescence can be obsd. upon excitation in the bound parts of the B state and instead a resonance Raman spectrum shows up superimposed on a broad fluore ...