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New Horizons for Perovskite Solar Cells Employing DNA-CTMA as the Hole-Transporting Material

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Interface and structural engineering of perovskite solar cells towards enhanced stability and performance

Masaud Hassan S Almalki

Perovskite solar cells have had a meteoric rise in the last decade achieving efficiencies that already rival the most established solar cells technologies. They are easily processed and have excellent optoelectronic properties that make them accessible for ...

EPFL2023

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Finding new hole-transporting materials (HTMs) suitable for replacing the state-of-the-art spiro-OMe-TAD is still challenging. In this work, newly synthesized diarylamine-substituted metal phthalocyanines (MPcs, M 1/4 Zn(II) or Cu(II)) functionalized with ...

ELSEVIER SCI LTD2022

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Crystallized p-type small-molecule semiconductors have great potential as efficient and stable hole transporting materials (HTMs) for perovskite solar cells (PSCs) due to their relatively high hole mobility, good stability and tunable HOMOs depending on th ...

2021

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Three hole-transporting materials (HTMs) were prepared following a straightforward synthetic route by cross-linking arylamine-based ligands with a simple thieno[3,2-b]thiophene (TbT) core. The novel HTMs were fully characterized with standard techniques to ...

2020

Inorganic and Hybrid Interfacial Materials for Organic and Perovskite Solar Cells

Mohammad Khaja Nazeeruddin

As organic solar cells (OSCs) and perovskite solar cells (PVSCs) move closer to commercialization, further efforts toward optimizing both cell efficiency and stability are needed. As interfaces strongly affect device performance and degradation processes, ...

2020

Zinc Phthalocyanine Conjugated Dimers as Efficient Dopant-Free Hole Transporting Materials in Perovskite Solar Cells

Felix Thomas Eickemeyer, Ulf Anders Hagfeldt, Kazuteru Nonomura, Bowen Yang, Brian Irving Carlsen, Marco Alejandro Ruiz Preciado, Natalie Flores Diaz, Desiré Molina Alcaide

Four ZnPc-dimers with 2,5-thienyl (ZnPc-th-ZnPc 1), 2,7-fluorenyl (ZnPc-flu-ZnPc 2), 3,6-bisthienylldiketopyrrolopyrrole (ZnPc-DPP-ZnPc 3) and 1,4-phenyl (ZnPc-p-ZnPc 4) bridges have been studied as dopant-free hole transporting materials (HTMs) in perovsk ...

WILEY-V C H VERLAG GMBH2020

Application of a Tetra-TPD-Type Hole-Transporting Material Fused by a Troger's Base Core in Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Paul Joseph Dyson, Zhaofu Fei, Cristina Roldán Carmona, Rui Xia

One of the obstacles to the commercialization of perovskite solar cells (PSCs) is the high price and morphological instability of the most common hole-transporting material (HTM) Spiro-OMeTAD. Herein, a novel HTM, termed V1160, based on four N,N '-bis(3-me ...

WILEY-V C H VERLAG GMBH2019

Indeno[1,2-b]carbazole as Methoxy-Free Donor Group: Constructing Efficient and Stable Hole-Transporting Materials for Perovskite Solar Cells

Ulf Anders Hagfeldt, Yinghui Wu, Zhiye Wang, Zhe Sun, Jialin Wang, Han Zhang

With perovskite-based solar cells (PSCs) now reaching efficiencies of greater than 20 %, the stability of PSC devices has become a critical challenge for commercialization. However, most efficient hole-transporting materials (HTMs) thus far still rely on t ...

WILEY-V C H VERLAG GMBH2019

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One of the challenges in the field of perovskite solar cells (PSC) is the development of inorganic hole-transporting-materials (HTM) suitable for solution-processed deposition, in order to have cheaper, more stable and scalable devices. Herein, we report t ...

2019

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A cobalt-catalyzed cyclotrimerization of bis(aryl)alkyne is used as an innovative tool to obtain hole-transport materials (HTMs). The novel HTM containing six units of oligotriarylamine (HAB1), characterized by UV-vis, cyclic voltammetry, DFT, and thermogr ...

AMER CHEMICAL SOC2019