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A search for the rare decays B-s(0)->mu(+)mu(-) and B-0 -> mu(+)mu(-) is performed at the LHCb experiment using data collected in pp collisions corresponding to a total integrated luminosity of 4.4 fb(-1). An excess of B-s(0) -> mu(+)mu- decays is observed with a significance of 7.8 standard deviations, representing the first observation of this decay in a single experiment. The branching fraction is measured to be B(B-s(0) -> mu(+)mu(-)) = (3.0 +/- 0.6(-0.2)(+)(0.3)) x 10(-9), where the first uncertainty is statistical and the second systematic. The first measurement of the B-s(0) -> mu(+)mu(-) effective lifetime, tau(B-s(0)-> mu(+) mu(-)) = 2.04 +/- 0.44 +/- 0.05 ps, is reported. No significant excess of B-0 -> mu(+)mu(-) decays is found, and a 95% confidence level upper limit, B(B-0 -> mu(+)mu(-) ) < 3.4 x 10(-10), is determined. All results are in agreement with the standard model expectations.
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