Tunable few-optical cycle pulses and advanced ultrafast spectroscopic techniques
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This thesis reports on results of three different experiments of photo-induced structural dynamics in the condensed phase, investigated by time-resolved pump-probe spectroscopy with femtosecond time-resolution. In the first part, we address the ultrafast d ...
The present work is devoted to the study of the dynamics of multi-photon processes in semiconductor heterostructures. A time-dependent description is important for understanding in detail the transient response of semiconductors excited by ultrashort optic ...
A new femtosecond pump-probe spectroscopy technique is demonstrated that permits the high-speed, parallel acquisition of pump-probe measurements at multiple wavelengths. This is made possible by use of a novel, two-dimensional smart pixel detector array th ...
Infrared spectroscopy using semiconductor lasers is a promising technique for trace gas detection. It allows a continuous and real time monitoring of several species, with a high sensitivity and a good selectivity. Among all the possible methods two are pa ...
A new method for simultaneously acquiring pump-probe signals at several wavelengths using a smart pixel detector array and broadband femtosecond laser has been demonstrated and promises to be a powerful technology for performing rapid, high sensitivity, wa ...
Sample prepn. and ligand complex prepn. of Hb I from Lucina pectinata were performed to obtain ultrafast data on ferric HbI-NO, HbI-N3, HbI-H2S and metHbI complexes that suggest a mechanism for the photoinduced redn. of HbI species. Formation of a transien ...
In a pump-probe experiment, we have been able to control, with phase-locked probe pulses, the ultrafast nonlinear optical emission of a semiconductor microcavity, arising from polariton parametric amplification. This evidences the coherence of the polarito ...
A novel spectral phase conjugation scheme by three-wave mixing is proposed. It is shown that a phase-conjugated and time-reversed replica of the incoming signal can be generated, if appropriate quasi-phase matching is achieved and the three-wave mixing pro ...
Femtosecond pump pulses are strongly attenuated in lithium niobate owing to two-photon absorption; the relevant nonlinear coefficient beta(p) ranges from similar to 3.5 cm/GW for lambda(p) = 388 nm to similar to 0.1 cm/GW for 514 nm. In collinear pump-prob ...
We present an experimental and theoretical study of sum-frequency generation of two infrared photons and one visible photon in a lithium iodate crystal. The sum-frequency light can be generated directly in a third-order process as well as in two subsequent ...