Ultrafast nuclear dynamics of the acetylene cation C2H2+ and its impact on the infrared probe pulse induced C-H bond breaking efficiency
Graph Chatbot
Chat with Graph Search
Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.
DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.
This thesis reports on results of three different experiments of photo-induced structural dynamics in the condensed phase, investigated by time-resolved pump-probe spectroscopy with femtosecond time-resolution. In the first part, we address the ultrafast d ...
The environment is important for the exact course of a chemical reaction. As an example of the strong influence of the environment on the reaction, this work studies the isomerization reaction of the chromophore retinal in the binding pocket of the protein ...
We apply gas-phase double resonance spectroscopic techniques to two helical peptides, Ac-Phe-(Ala)5-Lys-H+ and Ac-Phe- (Ala)10-Lys-H+, using electrospray ionization combined with photofragmentation in a cold, 22-pole ion trap. Despite the large size of the ...
A new femtosecond pump-probe spectroscopy technique is demonstrated that permits the high-speed, parallel acquisition of pump-probe measurements at multiple wavelengths. This is made possible by use of a novel, two-dimensional smart pixel detector array th ...
In this thesis report, we describe a novel home-built instrument designed to study the spectroscopy of biomolecular ions in the gas phase and at low temperature, and we present the first experimental results obtained on protonated aromatic amino acids. The ...
Ultrafast infrared transient absorption spectroscopy is used to study the photoinduced bimolecular electron transfer reaction between perylene in the first singlet excited state and 1,4-dicyanobenzene in acetonitrile and dichloromethane. Following vibratio ...
Infrared predissociation spectroscopy of nitric acid subsequent to vibrational overtone excitation reveals vibrational state mixing of the highly excited levels and probes the character of the coupled dark states. A visible dye laser excites the 4
A new method for simultaneously acquiring pump-probe signals at several wavelengths using a smart pixel detector array and broadband femtosecond laser has been demonstrated and promises to be a powerful technology for performing rapid, high sensitivity, wa ...
The ultrafast dynamics of electronic bubble formation upon excitation of the A(3ss) Rydberg state of NO trapped in solid H2 and D2 was studied by femtosecond pump-probe spectroscopy. The evolution of the spherical bubble is followed in real time by a probe ...