Graphite | EPFL Graph Search

Le graphite est une espèce minérale qui est, avec le diamant, la lonsdaléite et la chaoite, l'un des allotropes naturels du carbone. Sa formule chimique est « C » mais les formes natives permettent de retrouver des traces d'hydrogène (« H »), d'azote (« N »), d'oxygène (« O »), de silicium (« Si »), d'aluminium (« Al »), de fer (« Fe ») ou encore d'argile. Inventeur et étymologie

Les gisements historiques sont les mines britanniques de exploitées pour confectionner les mines de crayon dès le . Comme ce minéral ressemble au plomb que l'on utilise alors pour dessiner ou écrire, il reçoit le nom de plombagine. La plombagine remplace progressivement la mine de plomb dans les crayons. Ce n'est qu'en 1779 que le chimiste suédois Carl Wilhelm Scheele analyse la plombagine (qu'il utilise pour écrire) et prouve qu'elle est composée de carbone pur et non de plomb, montrant que ce minerai est une forme cristalline particulière du carbone.
C'est le minéralogiste allemand Abraha

Hydrothermally Stable Sulfonated Carbons as Solid Acid Catalysts for the Hydrolysis of Lignocellulose

David Ferdinand Scholz

The recycling of homogeneous acids imposes great challenges to the feasibility of lignocellulose hydrolysis processes. Although heterogeneous catalysts would offer a perspective to circumvent these challenges, conventional solid acids are instable under the hydrothermal conditions typical of hydrolysis processes. In this regard, acid functionalized carbons appear as auspicious alternatives due to the higher perseverance of carbon frameworks. The strong Brønsted acid sites in sulfonated carbons would be particularly well suited to catalyze the hydrolysis of cellulosic biomass. The utilization of these materials has so far been impeded by the controversy regarding the stability of sulfonic acid groups in carbons. Furthermore, it remains uncertain how the constraints imposed on the reaction system by the insolubility of lignocellulose influence the ability of solid acids to function as hydrolysis catalysts. This thesis shows that hydrothermally stable sulfonated carbons can be prepared by utilizing the structure-stability dependence of sulfonic acid groups in carbonaceous materials. The sulfonation of materials featuring a low degree of graphitization resulted in active solid Brønsted acid catalysts that however deactivated through the leaching of sulfonic acid groups. An in-depth physicochemical characterization of the catalysts paired with a systematic study of the stability of model sulfonic acids, revealed that the leaching-tendency is defined by substituent effects. Activating/deactivating substituents control the hydrothermal stability of aryl sulfonic acids by decreasing/increasing the tendency of the carbon-sulfur bond to undergo solvolysis. The presence of stabilizing and destabilizing substituents was found to be tunable by the temperature dependent decomposition of oxygen containing surface groups. Sulfonation of cellulose carbonized at 350°C resulted in a catalyst with 850 µmol g-1 hydrothermally (180 °C) stable sulfonic acid groups. Additionally, a hitherto unknown mode of deactivation was identified that proceeds by the ion-exchange of cationic impurities with protons of the active sites. This mode of deactivation can be fully overcome by implementing countermeasures to reverse or suppress ion-exchange processes. To tackle the limitations of homogeneous acids, the stable sulfonated carbons were used as catalysts in a semi-batch based lignocellulose hydrolysis process. It was found that the chemical recalcitrance and the insolubility of the substrate imposed strong limitations on the reaction with the catalyst and that soluble product formation occurred predominantly via auto-hydrolysis. The propensity of cellulose to undergo auto-hydrolysis could be enhanced by amorphizing its crystal structure through mechanical pretreatment in ball-mill. A heterogeneously catalyzed hydrolysis was achieved through mechanocatalytic processes facilitated by the concerted ball-milling (CBM) of the sulfonated carbon with the substrate. Sulfonic acid groups were pinpointed as active sites during the mechanocatalytic formation of soluble oligosaccharides. The secondary hydrolysis to monosaccharides in the semi-batch reactor was no longer constrained by the insolubility of the substrate. The combination of CBM pretreatment and hydrolysis in the semi-batch reactor was successfully extrapolated to the conversion of spruce fir wood to achieve yields in C5 and C6 derived products that are competitive with state-of-the-art diluted acid processes.

EPFL2019

Graphene-based Field-effect Transistors

Adarsh Singh Sagar

With transistors set to reach their smallest possible size in the next decade, the silicon chip is likely to change dramatically, or be replaced entirely. The transistor industry's path which has been largely shaped by Gordon Moore's famous prediction that the number of transistors on a silicon chip would double approximately every eighteen months, predicts a size of transistor which silicon technology cannot sustain, thereby ushering in a post-silicon age in semiconductors soon. In this scenario, graphene-derived nanomaterials are emerging as promising candidates for post-silicon electronics devices, with potential applications as atomically thin transistors and other nanoelectronic devices which incorporate quantum size effects. However, such claims still require a few important issues to be addressed first . This thesis focuses on demonstrating and studying field effect behaviour in graphene- and graphite-based devices. It describes the differences between the two types of graphene bilayers and the effect of their stacking order when placed in an electric field. The differences are studied using Scanning Photocurrent Microscopy, leading to the conclusion that the bottom layer in a misoriented bilayer effectively screens the charge carrier modulation when used in a back-gated FET configuration. A polymer electrolyte gate was employed on top to ultilise the enhanced carrier mobility within the top layer. The study is extended from bilayer graphene to multilayer graphene (graphite) while addressing a possibility of fabricating a field effect transistor on such a material. The thesis comments on the differences between each of these and their prospects in future applications. While emphasizing the effect of the substrate in such FETs, an intrinsic gain in a graphene-based FET of over one is shown at room temperature. The importance of both these aspects in the devices is also elucidated. Furthermore, the misoriented bilayer transistors were incorporated into phase-shift detectors, to exhibit their functioning in logical circuits. On the technical side, a novel method for fabricating graphene-based transistors on a lab-scale has been demonstrated which uses fluorescence quenching to distinguish the number of layers in a graphene stack.

EPFL2011

Spectrometer-free electron probe of ultrafast thermal dynamics in optically excited samples

Fabrizio Carbone

Cutting edge electron microscopes allow to probe the optical excitations in nanostructures with subangstrom spatial and femtosecond temporal resolution. In this study we discuss the prospects of probing the ultrafast out-of-equilibrium dynamics of plasmonic excitations in graphene and graphite samples. We show that, the plasmon excitation dynamics in nanostructured graphene and graphite can be traced through energy integrated and momentum resolved spectra of inelastically scattered electrons in contrast to more traditional energy-resolved spectroscopy approach, where highly-monochromatized electron beams and electron spectrometers with sufficient energy resolutions are essential. (C) 2021 The Author(s)